Results 91 to 100 of about 119,767 (324)

Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands [PDF]

open access: yes, 2014
The synthesis and catalytic activity of manganese(ii) complexes of two polyamine ligands is reported which highlights how a small structural change in the ligand affects the overall catalytic behaviour.
Al-Safadi, R   +5 more
core   +1 more source

Supramolecular Chemistry in Metal–Organic Framework Materials

open access: yesAdvanced Materials, EarlyView.
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ   +3 more
wiley   +1 more source

Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

open access: yesAdvanced Materials, EarlyView.
This review explores how in situ and operando spectroscopic techniques reveal the real‐time behavior of reticular materials, including MOFs and COFs. These methods track material formation and functionalization, structural changes, defect formation, dynamic responses to external triggers, and catalytic processes.
Bettina Baumgartner   +4 more
wiley   +1 more source

Upconversion Nanoparticle‐Covalent Organic Framework Core–shell Particles as Therapeutic Microrobots Trackable With Optoacoustic Imaging

open access: yesAdvanced Materials, EarlyView.
Upconversion nanoparticle‐covalent organic framework core–shell particles provide enhanced contrast for optoacoustic imaging by leveraging the optical absorption of upconversion luminescence within the covalent organic framework matrix. Beyond their role as contrast agents, these particles enable customizable therapeutic agent loading and release, as ...
Dong Wook Kim   +8 more
wiley   +1 more source

Probing structural relaxation in complex fluids by critical fluctuations

open access: yes, 2004
Complex fluids, such as polymer solutions and blends, colloids and gels, are of growing interest in fundamental and applied soft-condensed-matter science.
A. F. Kostko   +32 more
core   +1 more source

Mechanochemistry for Metal–Organic Frameworks and Covalent–Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms

open access: yesAdvanced Materials, EarlyView.
An overview is provided of the mechanochemistry of metal‐organic frameworks (MOFs) and covalent‐organic frameworks (COFs), highlighting opportunities and strategies for discovery, synthesis and reactivity studies of these materials. Mechanistic studies and comparisons to the mechanochemistry of organic solids are outlined, showcasing how advances in ...
Joseph M. Marrett   +3 more
wiley   +1 more source

Biphasic Ni‐MXene Quantum‐Confined Nanostructures: A Versatile Janus Platform for Advanced Energy Storage and Catalytic Oxidations

open access: yesAdvanced Materials, EarlyView.
A biphasic Ni‐MXene quantum‐confined nanostructure (Ni‐MJQD) serves as a Janus platform, simultaneously achieving high‐performance energy storage and efficient catalytic oxidation. The unique architecture enables superior energy storage performance and selective benzyl alcohol oxidation‐symbolizing “one stone, two birds” for sustainable energy and ...
Lagnamayee Mohapatra   +5 more
wiley   +1 more source

LDI, A Lipid Droplet Inhibitor, Disrupts Lipid Accumulation and Modulates Hepatic Lipid Profiles in Fatty Liver

open access: yesAdvanced Materials, EarlyView.
The lipid droplet inhibitor (LDI), templated with large‐pore mesoporous silica and functionalized with PKCα C1A and lipase, targets lipid degradation in fatty liver. The LDI maintains stable association with lipid droplets, thereby suppressing their formation and expansion.
Seunghee Kim   +12 more
wiley   +1 more source

Evolution of Collective, Radiative Plasmon Coupling in Confined, Soft Colloidal Films

open access: yesAdvanced Optical Materials, EarlyView.
Plasmon resonance coupling is continuously monitored during the uniaxial manipulation of a 2‐dimensional soft colloidal film containing hexagonally arranged spherical gold nanocrystals. This is realized by the in situ spectroscopic investigation of a monolayer of plasmonic core‐shell microgels confined at the air/water interface that is compressed in a
Déborah Feller   +7 more
wiley   +1 more source

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