Results 131 to 140 of about 153,481 (375)

Bifunctional Organocatalysts and Brønsted Bases in Cooperative Catalysis for the Asymmetric [4 + 2] Cycloaddition of In Situ‐Generated Dienes from Isochromane‐3,4‐Diones with Nitroalkenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Herein, the first asymmetric [4+2] cycloaddition is reported, utilizing in situ‐generated dienes from isochromane‐3,4‐diones and nitroalkenes, catalyzed by a bifunctional thiourea organocatalyst and Brønsted base cocatalysts, yielding highly enantioselective bridged and spiro lactones, with further investigations into novel reactivity and product ...
Mohammad Sadeq Mousavi   +2 more
wiley   +1 more source

Spectroscopic Conformational Analysis of Some 1,2-Dihalogeno Cyclohexanes. [PDF]

open access: bronze, 1957
P. Klæboe   +4 more
openalex   +1 more source

Influence of Ni concentration on α-MnO2 catalyst support and its potential application for benzene hydrogenation to cyclohexane

open access: yesKuwait Journal of Science
Herein, we report the influence of Ni at different concentrations on manganese oxide catalyst support (Ni/α-MnO2) prepared by the combined wet-impregnation and chemical reduction methods.
doaj   +1 more source

Catalytic Activity of Polynuclear vs. Dinuclear Aroylhydrazone Cu(II) Complexes in Microwave-Assisted Oxidation of Neat Aliphatic and Aromatic Hydrocarbons

open access: yesMolecules, 2018
One-dimensional (1D) polynuclear Cu(II) complex (1) derived from (5-bromo-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H2L) is synthesized and characterized by elemental analysis, IR spectroscopy, ESI-MS, and single crystal X-ray crystallography.
Manas Sutradhar   +3 more
doaj   +1 more source

Advances in adsorptive separation of benzene and cyclohexane by metal-organic framework adsorbents

open access: yes, 2021
S. Mukherjee   +6 more
semanticscholar   +1 more source

CO2‐to‐Cyclic Carbonate Transformation at Ambient Pressure Using a Mechanochemically Prepared Ti(III) Catalyst

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A Ti(III) complex synthesized mechanochemically catalyzes the cycloaddition of CO2 (1 bar) with terminal, internal, and trisubstituted epoxides. Mechanistic studies by density functional theory calculations reveal that the superior activity of Ti(III) compared to Ti(IV) arises from its lower oxophilicity, facilitating CO2 insertion into Ti–O bonds, as ...
Elena Álvarez‐Ruiz   +5 more
wiley   +1 more source

Low Temperature Oxidation of Cyclohexane: Uncertainty of Important Thermo-Chemical Properties

open access: yesEurasian Chemico-Technological Journal, 2018
The study of the standard formation enthalpy, entropy, and heat capacity for key species relevant to the low-temperature combustion of cyclohexane has been performed by applying the group additivity method of Benson. The properties of 18 Benson groups (8
M. Abbasi, N. Slavinskay, U. Riedel
doaj   +1 more source

At the cutting edge : structural analysis and chemical modification of the edges of mechanically cleaved graphene nanoribbons : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Nanoscience at Massey University, Manawatū, New Zealand [PDF]

open access: yes, 2017
The first decade of the new carbon nanomaterial graphene has been a time of great discovery and excitement as the exceptional properties of this material were uncovered and its promise for numerous applications realised.
Dykstra, Haidee Michaela
core  

Fe‐Photocatalyzed Decarboxylative Giese‐Type Reaction of α‐N, O or S Carboxylic Acids: Insight into the Mechanism of the Radical Formation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Electron‐deficient alkenes can be functionalized with α‐amino, α‐alkoxy and α‐alkylthio radicals formed by Fe‐photocatalyzed decarboxylation of the corresponding carboxylic acids. The reactions proceed under smooth ligandless conditions with inexpensive base and in the absence of oxidant. A mechanistic computational TD‐DFT study supports the occurrence
Fernando Pérez‐Maseda   +4 more
wiley   +1 more source

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