Results 161 to 170 of about 122,535 (318)

Precision Catalysis in Dehydrogenation of Liquid Organic Hydrogen Carriers: Molecular Structure‐Geometry‐Electronic Interplay for Enhanced Hydrogen Evolution

open access: yesCarbon Energy, EarlyView.
Atomic‐scale design principles for LOHC dehydrogenation: Tailoring geometric and electronic effects in metal catalysts to bridge the molecular structure of LOHC and dehydrogenation performance. ABSTRACT The advancement of hydrogen‐based energy systems necessitates innovative solutions for safe, efficient hydrogen storage and transportation.
Yongxiao Tuo   +8 more
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Photoinduced Electron Transfer (PET) as Key to Accelerate the Cycloreversion Reaction of Arylquadricyclanes

open access: yesChemistry – A European Journal, EarlyView.
It is demonstrated that the photoinduced cycloreversion of a methoxynaphthylquadricyclane in the presence of suitable photocatalysts gives quantitatively the corresponding norbornadiene. As this photochromic norbornadiene‐quadricyclane cycle has favorable properties for light energy conversion, this method provides a useful tool for the targeted ...
Julian Felix Maria Hebborn   +4 more
wiley   +1 more source

Diastereodivergent Synthesis of Multi-Substituted Cyclohexanes via Alkene Hydroamidation [PDF]

open access: gold
Yao Fu   +6 more
openalex   +1 more source

Selective Cyclohexane Oxidation Enhancement by Electronic Structures Regulation of Metal-Poly(Ionic Liquid)S

open access: green, 2023
Ruixia Liu   +7 more
openalex   +1 more source

Porphyrin‐Geländer–Helical Conjugated Banister Type Porphyrin Dyads

open access: yesChemistry – A European Journal, EarlyView.
Porphyrin arrays go chiral–A porphyrin Geländer macrocycle represents the intriguing prototype architecture of helically chiral butadiyne‐linked porphyrin arrays. This study combines synthetic, spectroscopic, and computational methods to shed light on its structure, chiroptical properties, and tunability, highlighting its promise for advancing ...
Joël F. Keller   +2 more
wiley   +1 more source

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