Diversity of ThDP‐Dependent Enzymes Forming Chiral Tertiary Alcohols
ChemBioChem, EarlyView.Chiral tertiary alcohols are widespread in nature and bioactive compounds; however, their asymmetric synthesis faces several challenges. This review outlines the toolbox of ThDP‐dependent enzymes able to produce tertiary alcohols through the formation of CC bond formation using ketones as acceptor substrates. Herein, the substrate scope, the diversity
Daniela Bjarnesen +4 more
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The Photochemical Reaction of Methyl Formate in Cyclohexane
, 1961 Kensuke Shima, Shigeru Tsutsumi
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NOTIZEN: Bildung und Reaktion Si-fluorierter 1.3.5-Trisila-cyclohexane / Formation and Reactions of Si-fluorinated 1,3,5-Trisilacyclohexanes [PDF]
, 1975 Gerhard Fritz, M. Portner
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ChemCatChem, EarlyView.Reaction sequence for the synthesis of methylated products through enzymatic decarboxylation of bio‐based hydroxycinnamic acids and subsequent direct methylation of the resulting styrene intermediates without any further isolation and purification steps.
Kamela Myrtollari +6 more
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Rate and Mechanism of Preparation of Adipic Acid by Single Stage Oxidation of Cyclohexane
, 1969 Kyugo TANAKA, Makoto Honda, Goro INOUE
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Kinetics of Charge Scavenging in γ-Irradiated Liquid Cyclohexane: A Comparison Between Different Ion–Electron Spacial Distribution Functions Used with Two Diffusion Approximations [PDF]
, 1971 Jean‐Pol Dodelet, Gordon R. Freeman
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ChemCatChem, EarlyView.The efficient and robust enantioselective organocatalytic methodology was developed for the conjugate addition of isoxazol‐5(4H)‐ones to aurone‐derived azadienes. This approach provided products featuring benzofuran and isoxazole rings with high yields and enantioselectivities.
Ricardo Torán +4 more
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Photosensitized Cis-Trans Isomerization of 2-Butenes in Cyclohexane
, 1969 深野 一幸, Shin Sato
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Mitochondria‐Catalyzed Activation of Anticancer Prodrugs
ChemCatChem, EarlyView.Prodrug C is a water soluble, monomeric compound accumulating in mitochondria of cancer cells, where it is activated in the reaction with mitochondrial H2O2. The activation leads to the release of camptothecin that causes cell cycle arrest in G2 phase and cancer cell death.
Michael Raucheisen +7 more
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Polymer Derived from 1, 4-Cyclohexane-dimethylol and Dimethylterephthalate
, 1962 御船 昭
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