Results 231 to 240 of about 83,989 (313)
In situ Raman spectroscopic characterization was applied to investigate supported catalytically active liquid metal solutions (SCALMS), revealing the role of hydrogen pretreatment and the formation of graphitic coke in propane dehydrogenation (PDH).
Sharanya Nair+7 more
wiley +1 more source
This study analyzes the electrochemical reduction pathways of 5‐hydroxymethylfurfural (HMF) on Cu electrodes. Our findings show that 2,5‐bis(hydroxymethyl)furan (BHMF) and 5‐methylfurfural (5‐MF) occurs through direct HMF reduction. Additionally, 5‐methylfurfural alcohol (MFA) can be produced either from HMF or 5‐MF, while 2,5‐dimethylfuran is derived ...
Jose Solera‐Rojas+5 more
wiley +1 more source
Synthesis and Electrochemical Investigations of a Binuclear [FeFe]‐Hydrogenase Mimic
Herein, a [FeFe]‐hydrogenase mimic with the benzene‐1,2‐dithiol ligand bearing two amino‐groups in 4‐ and 5‐position of the ligand is reported. The complex is active in the electrochemical hydrogen evolution reaction, and electrochemical investigation reveal an (E)ECEC mechanism for the hydrogen evolution reaction employing weak acids. Herein, a [FeFe]‐
Benedikt Callies+7 more
wiley +1 more source
A kinetically stable Wheland intermediate of the electrophilic aromatic substitution at ferrocene is isolated from the reaction of the diferrocenylphosphenium ion with the allene 2‐(trimethylsilyl)‐2,3‐pentadiene and fully characterized. The reaction of the diferrocenylphosphenium ion with four terminal allenes follows two different pathways, via allyl
Corina Stoian+7 more
wiley +1 more source
Physicochemical Properties of New Ionic Liquids and Plastic Crystal Based on Huckel Anions
To achieve optimal properties in organic ionic plastic crystals (OIPCs) and ionic liquids (ILs), new cations and anions must be investigated. A novel series of ILs and OIPC based on Huckel‐type anions were synthesised and characterised. Abstract There is increasing interest in ionic liquid electrolytes for battery applications due to their potential as
Azra Sourjah+5 more
wiley +1 more source
A polydentate ligand with multiple coordination patterns (bidentate N*N‐mode for Pt(II) and Re(I) centers, tridentate C^N*N‐motive for Pt(II)‐based complexes) is herein presented. The attained coordination‐chemical versatility in combination with different co‐ligands was employed to achieve sophisticated structural features and tunable photophysical ...
Stefan Buss+10 more
wiley +1 more source