Results 171 to 180 of about 2,523 (263)

A Chemically Recyclable 1,3,5‐Triazine‐Based Epoxy Thermoset Enabled by Nucleophilic Aromatic Substitution Reaction

open access: yesMacromolecular Rapid Communications, EarlyView.
High‐performance 1,3,5‐triazine epoxy networks are prepared via solvent‐free curing and recycled using nucleophilic aromatic substitution (SNAr) chemistry. This robust thermoset undergoes clean depolymerization into well‐defined building blocks for seamless repolymerization, achieving chemical recycling while preserving thermomechanical performance ...
Yi‐Ru Chen   +3 more
wiley   +1 more source

Tuning Degradation of Polylactic Acid via Size‐Controlled Silica Nanoparticles

open access: yesPolymer Engineering &Science, EarlyView.
Particle size emerges as a simple handle to program polymer degradation. By tailoring the size of silica nanoparticles, the degradation behavior of polylactide composites can be directed towards accelerated hydrolysis or enhanced composting‐induced disintegration without changing the polymer chemistry.
Xiangyu Zhu   +3 more
wiley   +1 more source

Ring-Opening of Aziridines Using Tethered Hemiketals. [PDF]

open access: yesJ Org Chem
Silver R   +3 more
europepmc   +1 more source

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

Homologous Ladder Cyclohexasilanes. [PDF]

open access: yesAngew Chem Int Ed Engl
Fang F   +6 more
europepmc   +1 more source

Highly Tunable Thermal Properties of Multifunctional Thiol‐Ene Networks Derived From Sugar‐Based Monomers

open access: yesJournal of Polymer Science, EarlyView.
Eleven allylated sugar frameworks combined with seven dithiol compounds create 77 thiol‐ene networks with a wide range of thermomechanical properties. Analysis based on composition reveals that both the sugar's functionality and the scaffold's structure work in conjunction with dithiol chemistry to influence the rubbery modulus, glass‐transition ...
Gether B. Coloma   +6 more
wiley   +1 more source

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