Aza-Diphosphazenanes: Inorganic Cyclohexane-like Connectors with Stereochemically Tunable Exit Vectors for Molecular and Macromolecular Chemistry. [PDF]
Land MA +4 more
europepmc +1 more source
A Brønsted acid-base approach for the net monoselective C-F substitution of (trifluoromethyl)alkanes. [PDF]
Coradi NJ, Bandar JS.
europepmc +1 more source
Synergistic decatungstate and Brønsted acid catalysis enables direct C-H indolation of alkanes and aldehydes. [PDF]
Peng G +8 more
europepmc +1 more source
Magneto‐structural correlation in bis‐μ‐hydroxido Cu(II) dimers: The out‐of‐plane angle (α) of bridging hydroxido groups critically influences the exchange coupling constant (J). A three‐dimensional correlation combining α and the Cu‐OH‐Cu angle (θ) enables computationally accurate J prediction.
Stefani Gamboa‐Ramirez +6 more
wiley +1 more source
Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions. [PDF]
Liang H, Zhu J, Wang L, Wendlandt AE.
europepmc +1 more source
Expedient Discovery of a Metallaphotoredox Cyanomethylation for Synthesizing α‐Aryl Nitriles
A metallaphotoredox cyanomethylation reaction has been developed for the synthesis of valuable α‐aryl nitrile intermediates. The methodology was successfully applied to diverse medicinally‐relevant substrates, providing an expedient route to anti‐cancer Senexin compounds, while also removing the need for toxic cyanide reagents. The mechanism was probed
Gemma C. Cook +6 more
wiley +1 more source
Probing the Microscopic Behavior of PFOS Clustering and Adsorption at LNAPL Interfaces; a PFOS-Water-Cyclohexane System. [PDF]
Sookhak Lari K +4 more
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1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Die geminale Difunktionalisierung leicht verfügbarer Bausteine ermöglicht einen schnellen Zugang zu molekularer Komplexität. Diese Arbeit stellt eine Strategie vor, um zwei unterschiedliche funktionelle Gruppen an einem Carbonylkohlenstoff zu installieren, indem dieser in eine Donor–Donor‐Diazo‐Verbindung überführt wird. Die Methode ist sowohl im Batch‐
Vincent George +13 more
wiley +1 more source
Oxidation of Cyclohexane to Cyclohexanol/Cyclohexanone Using Sol-Gel-Encapsulated Unspecific Peroxygenase from Agrocybe aegerita. [PDF]
Wu Y, Hollmann F, Musa MM.
europepmc +1 more source

