Results 11 to 20 of about 17,373 (214)
Comprehensive Thermodynamic Study of Alkyl-Cyclohexanes as Liquid Organic Hydrogen Carriers Motifs
Alkyl-cyclohexanes can be considered as suitable model compounds to understand the thermochemistry of aromatic compounds and their hydrogenated counterparts discussed as Liquid Organic Hydrogen Carrier systems.
Sergey P. Verevkin+4 more
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Reaction of linear conjugated enynones, 1,5-diarylpent-2-en-4-yn-1-ones, with malononitrile in the presence of lithium diisopropylamide LDA, as a base, in THF at room temperature for 3–7 h resulted in the formation of the product of dimerization ...
Anastasiya V. Igushkina+4 more
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Background: Up to 60% of pediatric surgical patients develop high levels of preoperative anxiety. This study compared the effects of oral combinations of midazolam and ketamine with oral midazolam alone for pediatric preanesthetic medication.
Get..lio Rodrigues de Oliveira Filho+3 more
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Novel Ring Systems: Spiro[Cycloalkane] Derivatives of Triazolo- and Tetrazolo-Pyridazines
In orderto synthesize new pyridazine derivatives anellated with different nitrogen heterocyclic moieties, spiro[cycloalkane]pyridazinones were transformed into the corresponding thioxo derivatives via a reaction with phosphorus pentasulfide. The reaction
Csilla Sepsey Für+6 more
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Entropy scaling based viscosity predictions for hydrocarbon mixtures and diesel fuels up to extreme conditions [PDF]
An entropy scaling based technique using the Perturbed-Chain Statistical Associating Fluid Theory is described for predicting the viscosity of hydrocarbon mixtures and diesel fuels up to high temperatures and high pressures. The compounds found in diesel
Gavaises, M.+4 more
core +1 more source
Single crystal X-ray diffraction is a powerful method to unambiguously characterize the structure of molecules with atomic resolution.
Cornelius Gropp, Nils Trapp
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Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane [PDF]
The authors are grateful to the Chinese Scholarship Council for Studentship support (ZF), to EPSRC for financial support and to the EPSRC National Mass Spectrometry Service at Swansea for analytical support.
Al-Maharik, Nawaf+4 more
core +2 more sources
Trisubstituted Cyclohexanes / Trisubstituted Cyclohexanes
C-Tertiarv vinylketones or the corresponding masked vinylketone derivatives react with pyrrolidin-2-one in the system sodium hydride.dimethylsulfoxide to substituted cyclohexanes of the 1,3.5- and sometimes additionally of the 1,2.4-type. Only acetophenone Mannich bases bearing a p-hydroxy or a dimethylamino group failed in cyclization.
Romanus Wille+3 more
openaire +2 more sources
Highly alkylated cyclohexanes. X-Ray crystal structures, force-field calculations, and conformations of cis/trans-1,4-disubstituted cyclohexane isomers [PDF]
The structures of mesylated cis- and trans-tetramethylshisool cis- 2 and trans-2 have been elucidated by single-crystal X-ray techniques. In cis-2 the isopropenyl group adopts an axial position in the crystal, and the structural data obtained are in good
Burkert+5 more
core +1 more source