Results 51 to 60 of about 2,523 (263)

Phase Equilibria in the Systems Acetone–Methanol, Acetone–Cyclohexane, Methanol–Cyclohexane, and Acetone–Methanol–Cyclohexane [PDF]

Canadian Journal of Chemistry, 1972
The vapor pressure and vapor composition of the methanol–cyclohexane system were investigated at temperatures ranging from 25 to 50°. The same properties of the binary systems: acetone–methanol and acetone–cyclohexane, as well as those of the ternary system: methanol–cyclohexane–acetone, were determined experimentally at 25°.
A. N. Campbell, S. C. Anand
openaire   +1 more source

A ring closing metathesis based approach for the spiroannulation of cyclopentanes and cyclohexanes. Formal synthesis of (+/-)-acorones

, 2001
An efficient ring closing metathesis (RCM.) reaction based approach was developed for the spiroannulation of cyclopentanes and cyclohexanes and its utility demonstrated in the formal synthesis of the spirosesquiterpenes ...
Babu, NC, Gharpure, SJ, Srikrishna, A, Rao, MS, Santosh J. Gharpure, N. Chandrasekhar Babu, A. Srikrishna, M. Srinivasa Rao   +7 more
core   +1 more source

Ribonucleotides Amplify Mitochondrial DNA‐Driven cGAS–STING Activation via FdUMP‐ribonucleotide Hybrid Particles to Potentiate Chemoimmunotherapy

Advanced Science, EarlyView.
This work develops a metabolic sharing strategy that employs cytidine monophosphate (CMP) to competitively reprogram floxuridine (FUDR) pyrimidine metabolism in colorectal tumor cells. Elevated intracellular FdUMP induces nucleotide imbalance, drives mitochondrial DNA release and cGAS‐STING innate immune cascade activation, and potentiates robust ...
Chao Wang, Chenxuan Zhao, Yesong Yao, Zhiwen Zou, Anxin Shi, Zhuo Feng, Mingkang Yang, Yue Yu, Yang Liu, Xuehui Rui, Jinhui Wu   +10 more
wiley   +1 more source

Magneto‐Sono‐Enhanced Nanozyme Catalysis Drives ROS‐Mediated Pathogen Killing and Mitophagy‐Linked Inflammation Control in Bacterial Pneumonia

Advanced Science, EarlyView.
Nebulized BN@NF nanozymes integrate boron nanosheets with Nd‐doped iron phosphide to form a sono‐magneto‐responsive Z‐scheme heterostructure. Under ultrasound and magnetic activation, BN@NF amplifies ROS generation, eradicates bacteria, disrupts biofilms, and reshapes pulmonary inflammation through NF‐κB suppression, mitophagy promotion, and M1‐to‐M2 ...
Xiaofeng Luo, Yundi Wu, Shuai Zhang, Huanran Qu, Shiyang Shao, Jianqiang Chen, Xilong Wu   +6 more
wiley   +1 more source

Strong hyperconjugative interactions limit solvent and substituent influence on conformational equilibrium: the case of cis-2-halocyclohexylamines

Beilstein Journal of Organic Chemistry, 2019
The presence of strong stereoelectronic interactions involving the substituents in cis-2-substituted cyclohexanes may lead to results different from those expected. In this work, we studied the conformational behavior of cis-2-fluoro- (F), cis-2-chloro- (
Camila B. Francisco, Cleverton S. Fernandes, Ulisses Z. de Melo, Roberto Rittner, Gisele F. Gauze, Ernani A. Basso   +5 more
doaj   +1 more source

Structure of asphaltenes occurring in oils of different chemical nature

Известия Томского политехнического университета: Инжиниринг георесурсов, 2018
The relevance of the work is caused by the need to obtain and generalize information on composition and structure of asphaltene components in oils of different chemical nature, since the features of structural characteristics of asphaltenes have a ...
Tatyana Victorovna Cheshkova, Valeriy Petrovich Sergun, Elena Yuryevna Kovalenko, Tatyana Anatolievna Sagachenko, Raisa Sergeevna Min   +4 more
doaj   +1 more source

Thickness‐Gradient Liquid Metal Connectors for Seamless Electrophysiological Sensors

Advanced Science, EarlyView.
Thickness‐gradient liquid metal interfaces with elastomeric substrates enable seamless integration between ultrathin skin‐conformal electrodes and external interconnects. The mechanically compliant connector reduces interfacial mismatch and supports stable ECG/EMG monitoring under bending and motion.
Jinyoung Kim, Jaejun Lee, Christopher E. Tabor, Vladimir V. Tsukruk   +3 more
wiley   +1 more source

A Comparative Study of the Catalytic Behaviour of Alkoxy-1,3,5-Triazapentadiene Copper(II) Complexes in Cyclohexane Oxidation

Inorganics, 2019
The mononuclear copper complexes [Cu{NH=C(OR)NC(OR)=NH}2] with alkoxy-1,3,5-triazapentadiene ligands that have different substituents (R = Me (1), Et (2), nPr (3), iPr (4), CH2CH2OCH3 (5)) were prepared, characterized (including the single crystal X-ray ...
Oksana V. Nesterova, Maximilian N. Kopylovich, Dmytro S. Nesterov   +2 more
doaj   +1 more source

Linkage Engineering Boosts Battery Performance of Two‐Electron Phenothiazine‐Based Polyamide Cathodes

Advanced Science, EarlyView.
Three phenothiazine‐based polyamides featuring gradually strengthened electron‐withdrawing linkers are developed as high‐voltage cathodes for lithium‐organic batteries. The linker motif serves not only as a structural bridge to suppress solubility, but also as a functional design element that governs optoelectronic properties and electron/ion transport
Shujuan Cao, Chunping Ren, Jing Qin, Xiujuan Wang, Xiaoming He   +4 more
wiley   +1 more source

Stabilizing Functional Nucleic Acids for Real‐Sample Diagnostics

Angewandte Chemie, EarlyView.
Functional nucleic acids enable programmable real‐sample diagnostics, but often lose function in complex biological matrices. This review highlights four stabilization levers—chemical, topological, architectural, and microenvironment/interface engineering—that preserve aptamer and DNAzyme performance in saliva, serum, urine, and stool, reframing ...
Soyeon Lee, Letizia Dondi, Amal Mathai, Connor Nurmi, Yingfu Li   +4 more
wiley   +2 more sources