Results 71 to 80 of about 2,523 (263)

Oxidative Coupling of ?,? - Di(cyclopentadienyl)alkyl-diides

CHIMIA, 1991
The CuII-induced oxidative coupling of ?,?-di(cyclopentadienyl)alkyl-diides 6 (n = 2 to 5) – as well as of 1,1,2,2-tetramethyl derivatives 10 and 13 of 6a (n = 2) – has been investigated in view of pertinent questions concerning the 'coupling ...
Shaochun You, Matthias Gubler, Markus Neuenschwander   +2 more
doaj   +2 more sources

Second‐Sphere Aromatic Substitutions That Tune H‐Atom Transfer Reactivity Observed for a Series of S = 1 Nonheme FeIV=O Complexes: An Enthalpy‐Entropy Compensation Effect

Angewandte Chemie, EarlyView.
A series of oxoiron(IV) complexes was synthesized to determine the impact of electronically tuned aromatic substitution in the secondary sphere of the ligand. Despite possessing identical electronic properties, they show significant differences in C─H oxidation reactions.
Abhishek Das, Jin Xiong, Victor G. Young Jr., Yisong Guo, Marcel Swart, Lawrence Que Jr.   +5 more
wiley   +2 more sources

Stereoselective Synthesis of Cyclohexanes via an Iridium Catalyzed (5 + 1) Annulation Strategy [PDF]

, 2018
An iridium catalyzed method for the synthesis of functionalized cyclohexanes from methyl ketones and 1,5-diols is described. This process operates by two sequential hydrogen borrowing reactions, providing direct access to multisubstituted cyclic products
Wasim M. Akhtar, Neil G. Stevenson (1378293), James R. Frost, Roly J. Armstrong (3987503), Neil G. Stevenson, Wasim M. Akhtar (3726214), Timothy J. Donohoe (1301979), Timothy J. Donohoe, James R. Frost (3726211), Roly J. Armstrong   +9 more
core   +1 more source

Phosphine Coordination to Ce, Nd, Np, and Pu in ArBiAMPtBu‐Supported Complexes and Their 2H and 13C Isotopologues

Advanced Science, EarlyView.
A dianionic ligand designed to encourage metal‐phosphine coordination—bis((3,5‐dimethylphenyl)amidomethyl)tertbutylphosphine (ArBiAMPtBu)—was employed in the synthesis of paramagnetic complexes of Ce, Nd, Np, and Pu, producing MI(ArBiAMPtBu)(thf)3.
Novan A. G. Gray, Yury Minko, Brenna K. Cashman, R. Joseph Lastowski, Adam R. Altenhof, Harris E. Mason, Daniel J. Lussier, Frank MacGregor, Andrew J. Gaunt, Aaron M. Tondreau   +9 more
wiley   +1 more source

Saturated and aromatic compounds of highly paraffinic oil and organic deposit

Известия Томского политехнического университета: Инжиниринг георесурсов, 2019
The urgency of the discussed issue is caused by the necessity to obtain the detailed information on the content and composition of hydrocarbons and heteroatomic components in high-paraffinic oils and the asfalto-resin-parafin deposits formed of the ...
Natalia Gerasimova, Elena Kovalenko
doaj   +2 more sources

Spatially Confined/Ligand‐Directed Ultrabright NIR‐AIE Nanoprobe for In Vitro Rapid Detection and In Situ Imaging of Bacterial Septic Arthritis

Advanced Science, EarlyView.
Inorganic PbS quantum dots spatially confine AIEgens and enable cooperative luminescence within a ligand‐directed core–shell–shell nanoassembly, generating ultrabright NIR PPANPs with enhanced fluorescence and photothermal performance. The platform enables 10‐min S.
Yujian Li, Jia Shu, Sijia Lv, Leilei Qin, Xuefeng Luo, PengCheng Xiao, Huan Cai, Xin Gao, Yan Zhao, Haotian Zhou, Yaji Yang, Zhenglin Zhu, Shijia Ding, Juan Li, Rui Chen, Wei Huang   +15 more
wiley   +1 more source

Supramolecular Cadmium‐Telluride Proteoliposomal Assemblies for Real‐Time Detection of Protein‐Catalyzed Pt(II)‐Complexes Transmembrane Translocation: Cu(I)‐Pumps Are Electrogenic Pt(II)‐Drug Uniporters

Angewandte Chemie, EarlyView.
Supramolecular mercaptosuccinic acid‐capped CdTe core‐type quantum dot‐encapsulated proteoliposome assemblies (MSA‐CdTe QD PLs) have been developed to study and unambiguously demonstrate real‐time transporter‐mediated turnover translocation of Pt(II)‐based complexes by transmembrane Cu(I) P‐type ATPase pumps (CopA).
Madujika A. Horadigala Gamage, Alessandra Barbanente, Nadeesha T. Liyana Withanage, Yalini H. Wijesundara, Jeremiah J. Gassensmith, Fabio Arnesano, Giovanni Natile, Gabriele Meloni   +7 more
wiley   +2 more sources

1,5-Induction in reactions between 2-alkoxy-(2-tributylstannylethylidene)cyclohexanes and aldehydes

Journal of the Brazilian Chemical Society, 2001
2-Methoxy(2-tributylstannylethylidene)cyclohexane 16 undergoes stereoselective transmetalation on treatment with tin(IV) chloride to generate the allyltin trichloride 19 which reacts with aldehydes to give the (Z)-(3-hydroxyalkylidene)-2 ...
Kumar Poonam, Thomas Eric J., Tray Daniel R.   +2 more
doaj  

Interfacial Salt Redistribution Enables Rapid Atmospheric Water Harvesting in a Biomimetic Multi‐Layer Hygroscopic Membrane

Advanced Science, EarlyView.
A biomimetic multi‐layer hygroscopic membrane redistributes salt toward an air‐accessible nanofiber interface, enabling rapid interfacial deliquescence while a brush‐like hydrogel promotes efficient liquid transport and storage. By decoupling vapor capture from bulk water storage, the membrane achieves fast sorption kinetics and enables rapid‐cycling ...
Fu‐Yao Zhong, Chao‐Yang Guo, Zai‐Dong Shao, Lu‐Bing Zhong, George Zheng Chen, Yaoyao Zheng, John L. Zhou, Yu‐Ming Zheng, Jun He   +8 more
wiley   +1 more source

Ti(II)-Mediated Tandem Inter- and Intramolecular Coupling Reaction of Unsaturated Hydrocarbons:  One-Pot Preparation of Cyclopentanes and Cyclohexanes from Readily Available Acyclic Starting Materials

, 2016
Ti(II)-Mediated Tandem Inter- and Intramolecular Coupling Reaction of Unsaturated Hydrocarbons:  One-Pot Preparation of Cyclopentanes and Cyclohexanes from Readily Available Acyclic Starting ...
Sentaro Okamoto (1702069), Fumie Sato (2681434), Kandasamy Subburaj (2982975)   +2 more
core   +1 more source