Synthesis of a highly active Nb2O5 for 1,2-cyclohexanediol production
A commercial niobium oxide was used to form a gelled material, which was lyophilized producing a novel polyoxoniobate catalyst (L-AmNbO) containing peroxo groups.
Carlos G.O. Bruziquesi+8 more
doaj
Absolute configuration of vouacapen-5α-ol
The title compound, C20H30O2, {systematic name: (4aR,6aS,7R,11aS,11bR)-4,4,7,11b-tetramethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-4a-ol}, is a cassane furanoditerpene which was isolated from the roots of Caesalpinia ...
Hoong-Kun Fun+3 more
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A Mild Catalytic Oxidation System: FePcOTf/H2O2 Applied for Cyclohexene Dihydroxylation
Iron (III) phthalocyanine complexes were employed for the first time as a mild and efficient Lewis acid catalyst in the selective oxidation of cyclohexene to cyclohexane-1,2-diol.
Baocheng Zhou, Wenxing Chen
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Oxidoperoxidomolybdenum(VI) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties [PDF]
Oxidoperoxido–molybdenum(VI) complexes containing acylpyrazolonate ligands were obtained by reaction of [Mo(O)(O)2(H2O)n] with the corresponding acylpyrazolone compounds HQR.
Begines, Emilio+7 more
core +1 more source
Epoxidation of cyclohexene with cyclohexyl hydroperoxide
Objectives. To investigate the regularities of the process of joint production of epoxycyclohexane, cyclohexanol, and cyclohexanone using the cyclohexene epoxidation reaction with cyclohexyl hydroperoxide in the presence of an ammonium paramolybdate ...
E. A. Kurganova+8 more
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Crystal structure of 5-(4-benzyloxyphenyl)-3-(4-methoxyphenyl)-6-methylcyclohex-2-en-1-one
The title compound, C27H26O3, crystallized with two independent molecules (A and B) in the asymmetric unit. In molecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings ...
S. Sathya+4 more
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Interfacial Photoelectrochemistry in Organic Synthesis
Photoelectrodes have traditionally enjoyed widespread attention as heterogeneous catalysts for the activation of water and CO2 in energy research, while photoelectrochemistry with homogeneous molecular catalysts dominates the activations of more complex molecules in organic synthesis.
Gabriel Chan+4 more
wiley +1 more source
Shape-controlled nanostructured MoO3/CeO2 catalysts for selective cyclohexene epoxidation
This study reported a vital role of CeO2 shape on the structure-activity properties of MoOx/CeO2 catalysts for cyclohexene epoxidation. Uniform dispersion of MoOx on the surface of shape-controlled CeO2 nanocubes (average particle size: 23.5 nm) and ...
Putla Sudarsanam+2 more
doaj
Ecofriendly Palladium on Wool Nanocatalysts for Cyclohexene Hydrogenation
Use of natural wool fiber supports in the fabrication of novel composite materials incorporating metal nanoparticles, which offer the possibility of “environmentally friendly” catalytic materials, has been investigated.
Sedigheh Ghadamgahi+2 more
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The Chemistry and Biology of the Tetrodotoxin Natural Product Family
Tetrodotoxin is best known as the poison of the pufferfish, which is a delicacy in Japanese cuisine. Its toxicity arises from the selective blockage of NaV channels, which is depicted for the NaV1.7 pore, highlighting the DEKA motif, which permeates sodium ions.
Benedikt Nißl+6 more
wiley +1 more source