Results 31 to 40 of about 1,519 (209)
Mo and Pt Complexes of an Azine Phosphine with a Ferrocene Moiety [PDF]
OUSL JournalCondensation of the phosphino hydrazone Z-PPh2CH2C(But)=NNH2 II with ferrocene carboxaldehyde, CpFe(C5H4CHO) produced the azine monophosphine Z,E-PPh2CH2C(But)=N-N=CH(C5H4)FeCp (Z,E-LH).
Sarath D. Perera
doaj +1 more source
Activació de l’enllaç CH d’imines amb compostos de ruteni [PDF]
, 2020 Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2020, Tutor: Jaume Granell SanvicenteThe synthesis of different Schiff’s bases has been described in order to use them as ligand for the subsequent cyclometallation ...
Martínez Segura, Albert
core +6 more sources
Molecules, 2021 Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
doaj +1 more source
Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex [PDF]
Organometallics, 2022 Quantitative catalytic nucleophilic fluorination of a range of acyl chlorides to acyl fluorides was promoted by a cyclometallated rhodium complex [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)- RhCl] (1). 1 can be prepared in high yields from commercially available starting materials using a one-pot method.
Patrick J. Morgan +4 more
openaire +4 more sources
Luminescent cyclometalated gold(iii) complexes [PDF]
Dalton Transactions, 2011 Many luminescent gold(I) compounds are known, but in the vast majority of gold(III) complexes reported until recently, room temperature emission in fluid solution does not occur. As for other d(8) and d(6) metals, the key to obtaining gold(III) compounds with favorable luminescence properties seems to be the use of cyclometalating ligands that ensure ...
Bronner, Catherine, Wenger, Oliver S.
openaire +3 more sources
Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
Nature Communications, 2019 Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight ...
Keke Meng +5 more
doaj +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Angewandte Chemie, Volume 138, Issue 37, 7 September 2026.Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Synthesis of rhodium(III) complexes with tris/tetrakis-benzimidazoles and benzothiazoles - quick identification of cyclometallation by nuclear magnetic resonance spectroscopy [PDF]
, 2009 Reactions of rhodium(III) halides with multidentate N, S-heterocycles, (LH3) 1,3,5-tris(benzimidazolyl)benzene (L1H3; 1), 1,3,5-tris(N-methylbenzimidazolyl) benzene (L2H3; 2) and 1,3,5-tris(benzothiazolyl)benzene (L3H3; 3), in the molar ratio 1 : 1 in ...
Chandrashekhar, N. +2 more
core +1 more source
Dalton Transactions, 2019 Reactions of the mesityl(amidinato)tetrylenes E(tBu2bzam)Mes (tBu2bzam = N,N'-bis(tert-butyl)benzamidinate; Mes = mesityl; E = Ge (1Ge), Si (1Si)) with the iridium precursors [Ir2(μ-Cl)2(η4-cod)2] (cod = 1,5-cyclooctadiene) and [Ir2Cl2(μ-Cl)2(η5-Cp*)2 ...
J. Cabeza +4 more
semanticscholar +1 more source
Formazanate Complexes of Bis-Cyclometalated Iridium [PDF]
Inorganic Chemistry, 2019 In this work we describe a series of bis-cyclometalated iridium(III) formazanate complexes, expanding the coordination chemistry of the redox-active formazanate class to iridium. A total of 18 new complexes are described, varying the substituent pattern on the formazanate and the identity of the cyclometalating ligand on iridium.
Evanta Kabir +4 more
openaire +2 more sources