A new type of Rh(i)-catalyzed intramolecular [2 + 2 + 1] cycloaddition of diynes and the N-terminal of a diazo moiety is reported. This study is the first attempt to combine oxidative cyclometallation with carbene migratory insertion.
Wang, Bo +3 more
core +1 more source
Dimethylplatinum(I1) complexes, PtR2(L), have been made by reaction of [PtR2(mu-SEt2)]2 with a range of polydentate nitrogen donor ligands containing one or more pyrazol-l-y1 (pz) donor groups, including the new ligand bis(pyrazol-1-yl)(thien-2-yl ...
Honeyman, RT (15479867) +1 more
core
Synthesis of vinyl-substituted alcohols using acetylene as a C2 building block. [PDF]
Lin Z, Liu B, Wang Y, Li S, Zhu S.
europepmc +1 more source
Rh(i)-catalyzed dimerization of ene-vinylidenecyclopropanes for the construction of spiro[4,5]decanes and mechanistic studies. [PDF]
Ning C, Rui KH, Wei Y, Shi M.
europepmc +1 more source
Tuning Ruthenium Carbene Complexes for Selective P-H Activation through Metal-Ligand Cooperation. [PDF]
Feichtner KS +5 more
europepmc +1 more source
Pyridine C(sp2)-H bond functionalization under transition-metal and rare earth metal catalysis. [PDF]
Sindhe H +6 more
europepmc +1 more source
Tunably strained metallacycles enable modular differentiation of aza-arene C-H bonds. [PDF]
Xi L, Wang M, Liang Y, Zhao Y, Shi Z.
europepmc +1 more source
A tetranuclear nickel hydride cluster capable of reversible activation of aromatic and aliphatic C-H bonds. [PDF]
Sunami K +13 more
europepmc +1 more source
Iridium catalyzed regiodivergent functionalization of all three C-H bonds of arenes by a single ligand. [PDF]
Das J +8 more
europepmc +1 more source
Mechanism-Guided Development of Directed C-H Functionalization of Bicyclo[1.1.1]pentanes. [PDF]
Bunnell A +7 more
europepmc +1 more source

