Atom Transfer Radical Reactions as a Tool for Olefin Functionalization : On the Way to Practical Applications [PDF]
Transition-metal-catalyzed atom transfer radical reactions of halogenated compounds with olefins constitute a versatile tool in organic synthesis within the area of C–C bond forming transformations.
Muñoz Molina, José María +2 more
core +1 more source
Redox-mediated reactions of vinylferrocene: Toward redox auxiliaries [PDF]
Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels–Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state.
Cooke, Graeme +5 more
core +1 more source
Performance Prediction of the Catalyst PR-81 at the Production Unit Using Mathematical Modeling Method [PDF]
Using programming support environment FreePascal and FreeBasic, the program providing to calculate values of efficient rate constants for hydrogenation reactions of benz- and dibenzothiophenes in the process of diesel fuel hydrofining, is developed.
Beliy, Aleksandr Sergeevich +4 more
core +1 more source
Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones [PDF]
Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all ...
Beattie, N. A. +4 more
core +1 more source
Dispersion‐Enhanced Nitrogen‐Centered Photocatalysis of the Direct Hydrogen Atom Transfer
Nitrogen‐centered acridine photocatalysts for direct hydrogen atom transfer have been developed, leveraging dispersion interactions to enhance photocatalytic activity. This approach enables diverse functionalization reactions of strong C─H bonds even under cryogenic conditions and provides a new strategy for boosting the efficiency of direct HAT ...
Jiasong Zhang +16 more
wiley +2 more sources
Extension of the single-event microkinetic model to alkyl substituted monoaromatics hydrogenation on a Pt catalyst [PDF]
The Single-Event Micro Kinetic (SEMK) methodology, which had been successfully applied to benzene hydrogenation on a Pt catalyst, has now been extended toward substituted monoaromatics, that is, toluene and o-xylene.
Bera, Tapan, Marin, Guy, Thybaut, Joris
core +2 more sources
Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane + Oxygen, Cyclopentane + Nitrogen, and Cyclopentane + Hydrogen [PDF]
In this work, four-phase hydrate equilibrium data for each of the systems cyclopentane (CP) + water + hydrogen, CP + water + nitrogen, and CP + water + oxygen were measured and are reported in the temperature range of 281.3-303.1 K and the pressure range of 2.27-30.40 MPa. Measurements were made using an isochoric method.
Du Jianwei +3 more
openaire +2 more sources
Is the Ring Conformation the Most Critical Parameter in Lipase-Catalysed Acylation of Cycloalkanols? [PDF]
Financial support of this work by the Spanish Ministerio de Ciencia y Tecnología (Project No. PPQ-2001-2683) and by Principado de Asturias (Project No.
Gotor Santamaría, Vicente Miguel +2 more
core +2 more sources
Enantioselective isothiourea catalysed Michael-Michael-lactonisation cascade; synthesis of δ-lactones and 1,2,3,4-substituted cyclopentanes [PDF]
The authors thank the EPSRC (ERTR – grant code EP/J500549/1; ABF - grant code EP/J018139/1), the Spanish government for a FPU Fellowship and the University of Seville (V Plan Propio de Investigación) for financial support (PER).
Elías-Rodríguez, Pilar +3 more
core +1 more source
Diastereoselective Photoredox-Catalyzed [3 + 2] Cycloadditions of N-Sulfonyl Cyclopropylamines with Electron-Deficient Olefins [PDF]
A highly diastereoselective, visible-light-induced [3 + 2] cycloaddition between N-sulfonyl cyclopropylamines and electron-deficient olefins is reported.
Aggarwal, Varinder K. +3 more
core +2 more sources

