Results 31 to 40 of about 5,087 (177)
, 2020 The synthesis of some highly substituted three-dimensional cyclopentanes with multiple chiral centers and with high regiochemical and stereochemical diversity has been accomplished starting from cyclopentadiene-derived aminocyclopentenecarboxylic acids ...
Nonn Melinda +7 more
core +2 more sources
Clathrate hydrate crystallization
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Clathrate hydrate crystallization has been an area of interest to chemical engineers from the point of view of crystal structure, thermophysical properties, phase equilibria, kinetics, industrial applications, and environmental (climate change) implications.
Peter Englezos
wiley +1 more source
, 2016 5-endo-trig Radical Cyclizations: A New Means to the Stereoselective Synthesis of Cyclopentanes and ...
Stéphane Bogen (2995686) +1 more
core +2 more sources
The Expanding Role of Diazirines in Synthetic Methodology
European Journal of Organic Chemistry, EarlyView.Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic +3 more
wiley +1 more source
Cyclopentanes from N-amino-glyconolactams. A synthesis of mannostatin A
, 2003 Oxidation of a N-amino-ribonolactam with lead tetraacetate yields two cyclopentanes; the major one was transformed into the α-mannosidase inhibitor mannostatin ...
Hu, Guixian +3 more
core +1 more source
Journal of the Chinese Chemical Society, EarlyView.A trinuclear manganese complex supported by the 7‐Dipy scaffold undergoes controlled multielectron oxidation from Mn(II)3 to high‐valent Mn(IV)3 states. Spectroscopic signatures, including 16‐line and geff ≈ 5 EPR features, reveal stepwise redox accumulation. The oxidized Mn3 cluster mediates efficient oxygen‐atom transfer to strong CH bonds, enabling
Yu‐Hsuan Chen, Peter Ping‐Yu Chen
wiley +1 more source
Thiolate Salt Mediated Dynamic Silyl Ether Exchanges for Polymer Network Design and Deconstruction
Macromolecular Rapid Communications, EarlyView.This work introduces thiolate salts as mediators for dynamic silyl ether exchange. This platform enables the synthesis of reprocessable covalent adaptable polymer networks (CANs) and allows for sterically controlled, and tunable deconstruction of silyl ether‐containing thermosets.
Pierce T. Bombard +9 more
wiley +1 more source
Hydroxamic Acids as HDAC Inhibitor Drug Leads for Malaria
Medicinal Research Reviews, EarlyView.ABSTRACT Malaria is a global health threat, with an estimated 282 million cases and 610,000 malaria‐associated deaths reported in 2024. Most mortality is due to infection by Plasmodium falciparum parasites, with the highest burden occurring in Sub‐Saharan Africa.
Wisam A. Dawood +7 more
wiley +1 more source
Delivering Sulfate to LNAPL Body for Enhanced Source Zone Depletion (ESZD)
Groundwater Monitoring &Remediation, EarlyView.Abstract This field pilot study evaluates the feasibility of applying sulfate to a light non‐aqueous phase liquid (LNAPL) body for achieving enhanced source zone depletion (ESZD) at a refinery site. Two rounds of gypsum land application (GLA) delivered sulfate to an 8000 ft2 area encompassing LNAPL‐containing monitoring wells MW‐2 and MW‐3, while MW‐1 ...
Ravi Kolhatkar +2 more
wiley +1 more source
Synergistic catalysis: asymmetric synthesis of cyclopentanes bearing four stereogenic centers
, 2017 We present a formal [3+2] cycloaddition based on synergistic catalysis. Vinylcyclopropanes derived from cyanoesters react with enals by dual activation using palladium(0) and secondary amines to form the corresponding cyclopentanes in good yields and ...
Contamine, Clotilde +9 more
core +1 more source