Results 131 to 140 of about 19,839 (247)
Electrocatalytic polarity inversion of azlactones unlocks their coupling with electron‐rich reaction partners. Triarylamine‐mediated oxidation of the azlactone enolate generates an electrophilic radical intermediate that undergoes selective C4 functionalization with diverse SOMOphiles.
Paula Rodríguez +6 more
wiley +2 more sources
Enantioselective Gas Chromatographic Analysis of Cyclopropane Derivatives [PDF]
Chirasil-β-Dex was used as chiral stationary phase for the enantioselective gas chromatographic analysis of several new chiral cyclopropane derivatives.
Lacrampe, F. +5 more
core
Cyclopropane-Alkene Metathesis by Gold(I)-Catalyzed Decarbenation of Persistent Cyclopropanes
A gold(I)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent
Mato, Mauro +3 more
core
VIBRATIONAL SPECTRA AND CONFORMATIONS OF SOME SUBSTITUTED CYCLOPROPANE DERIVATIVES
Author Institution:The infrared and Raman of vinyloxirane, epibromihydrin, and (bromomethy1)-cyclopropane have been recorded. The data for the liquid and vapor phases of vinyloxirane are consistent with the presence of three conformations, and the s ...
Wurrey, C. J. +2 more
core +1 more source
Simple calcium bis(amido) compounds are exceptionally potent hydrophosphination catalysts in DMSO solution. At ambient temperature or under irradiation, this catalyst successfully engages all manner of unsaturated substrates with primary and secondary phosphines with more than 100 examples of high conversion.
Moniruzzaman Moniruzzaman, Rory Waterman
wiley +1 more source
The Expanding Role of Diazirines in Synthetic Methodology
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic +3 more
wiley +1 more source
Toward Chemoselective Modification of Selenocysteine-Containing Biomolecules Via Doubly Activated Cyclopropanes. [PDF]
Yamakoshi H +8 more
europepmc +1 more source
Carbon Insertion into Electron-Deficient (Aza)indoles via a Radical-Polar Crossover Strategy. [PDF]
Roth AD +5 more
europepmc +1 more source

