Results 111 to 120 of about 19,839 (247)

Modular synthesis of a new family of tripodal ligands, all-cis-1,2,3-tris(diphenylphosphinomethyl)cyclopropane and relatives

open access: yes, 2007
Bisbenzyl-protected all-cis-1,2,3-tris(hydroxymethyl)cyclopropane has been obtained in three steps from commercially available cis-2-butene-1,4-diol (75% overall yield) and used to prepare a number of all-cis-1,2,3-trisubstituted cyclopropane derivatives.
de Meijere, Armin   +2 more
core   +1 more source

Cytoplasmic Lipid Membrane Biogenesis in Prokaryotes: From Soluble Lipid Building Blocks to a Dynamic and Functional Boundary Layer

open access: yesChemBioChem, Volume 27, Issue 20, 28 October 2026.
Lipid membranes are fundamental to all prokaryotic life. Besides acting as barrier, by orienting as hydrophobic bilayer, lipids are involved in a wide variety of other cellular processes. As a consequence, prokaryotic membranes are dynamic entities that switch their lipid composition as required; a process that requires tight interplay with the lipid ...
Sergiy Gan, Marten Exterkate
wiley   +1 more source

Stereochemical Control in the Matteson Reaction

open access: yesChemistry – A European Journal, Volume 32, Issue 40, 27 October 2026.
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley   +1 more source

EXPERIMENTAL STUDY ON PREVENTION AGAINST EXPLOSION OF ANESTHETIC GAS (ETHER AND CYCLOPROPANE) PART II. ON THE EXPLOSIVE LIMITS OF ETHER GAS AND CYCLOPROPANE AND THE INDOOR AIR CONDITIONING [PDF]

open access: yes, 1957
The influences of temperature and humidity in the operating room on the lower explosive limit were studied and the relation of the indoor air conditioning to the precaution against ignition was clarified.
Sakashita, Noboru
core  

The microwave spectrum of cyclopropane [middle dot] ammonia. A novel structure for cyclopropane complexes

open access: yes, 1994
The microwave spectrum of the cyclopropane[middle dot]ammonia (C3H6[middle dot]14NH3) complex has been observed using a pulsed nozzle, Fourier-transform microwave spectrometer. The spectrum is characteristic of a symmetric top, B0=2668.7161(4), with free
Susan E. Forest   +3 more
core   +1 more source

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu   +2 more
wiley   +1 more source

Highly stereoselective synthesis of 2-Azabicyclo[3.1.0]hex-3-ene and 5-Azatricyclo[4.1.0.02,4]heptane scaffolds via Rh-catalyzed cyclopropanation of pyrrole

open access: yesJournal of Saudi Chemical Society
A rhodium-catalyzed cyclopropanation of pyrrole derivatives with electron-rich cyclopropenes is reported for the efficient access to vinyl functionalized cyclopropane fused pyrrolidine scaffolds, including 2-azabicyclo[3,1,0]hex-3-ene and 5-azatricyclo[4.
Dongyan Ju   +5 more
doaj   +1 more source

Selective N‐Functionalization of Pyrazoles

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 40, 27 October 2026.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek   +2 more
wiley   +1 more source

Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols

open access: yesAngewandte Chemie, Volume 138, Issue 43, 19 October 2026.
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang   +3 more
wiley   +2 more sources

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