Results 111 to 120 of about 19,839 (247)
Bisbenzyl-protected all-cis-1,2,3-tris(hydroxymethyl)cyclopropane has been obtained in three steps from commercially available cis-2-butene-1,4-diol (75% overall yield) and used to prepare a number of all-cis-1,2,3-trisubstituted cyclopropane derivatives.
de Meijere, Armin +2 more
core +1 more source
Lipid membranes are fundamental to all prokaryotic life. Besides acting as barrier, by orienting as hydrophobic bilayer, lipids are involved in a wide variety of other cellular processes. As a consequence, prokaryotic membranes are dynamic entities that switch their lipid composition as required; a process that requires tight interplay with the lipid ...
Sergiy Gan, Marten Exterkate
wiley +1 more source
Stereochemical Control in the Matteson Reaction
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley +1 more source
EXPERIMENTAL STUDY ON PREVENTION AGAINST EXPLOSION OF ANESTHETIC GAS (ETHER AND CYCLOPROPANE) PART II. ON THE EXPLOSIVE LIMITS OF ETHER GAS AND CYCLOPROPANE AND THE INDOOR AIR CONDITIONING [PDF]
The influences of temperature and humidity in the operating room on the lower explosive limit were studied and the relation of the indoor air conditioning to the precaution against ignition was clarified.
Sakashita, Noboru
core
The microwave spectrum of the cyclopropane[middle dot]ammonia (C3H6[middle dot]14NH3) complex has been observed using a pulsed nozzle, Fourier-transform microwave spectrometer. The spectrum is characteristic of a symmetric top, B0=2668.7161(4), with free
Susan E. Forest +3 more
core +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
A rhodium-catalyzed cyclopropanation of pyrrole derivatives with electron-rich cyclopropenes is reported for the efficient access to vinyl functionalized cyclopropane fused pyrrolidine scaffolds, including 2-azabicyclo[3,1,0]hex-3-ene and 5-azatricyclo[4.
Dongyan Ju +5 more
doaj +1 more source
Selective N‐Functionalization of Pyrazoles
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek +2 more
wiley +1 more source
Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang +3 more
wiley +2 more sources

