Results 91 to 100 of about 19,839 (247)

A Simple Divergence from Asymmetric Cyclopropane to Lactone Annulation

open access: yes, 2016
A Simple Divergence from Asymmetric Cyclopropane to Lactone ...
Shinji Tanimori (2041681)   +2 more
core   +1 more source

The continuing significance of chiral agrochemicals

open access: yesPest Management Science, Volume 81, Issue 4, Page 1697-1716, April 2025.
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley   +1 more source

Characterization and analysis of the cotton cyclopropane fatty acid synthase family and their contribution to cyclopropane fatty acid synthesis

open access: yesBMC Plant Biology, 2011
Background Cyclopropane fatty acids (CPA) have been found in certain gymnosperms, Malvales, Litchi and other Sapindales. The presence of their unique strained ring structures confers physical and chemical properties characteristic of unsaturated fatty ...
Rawat Richa, Yu Xiao-Hong, Shanklin John
doaj   +1 more source

Five Decades of Dispute: A Triptych. Roald Hoffmann

open access: yesThe Chemical Record, EarlyView.
This article examines the historical Corey–Woodward controversy through Roald Hoffmann's personal perspective, completing a triptych on the prolonged dispute. Drawing on archival records, contemporaneous correspondence, and extensive interviews, it reconstructs Hoffmann's interactions with Corey and Woodward from the 1960s onward.
Jeffrey I. Seeman
wiley   +1 more source

Oxaziridines: Versatile Reagents in Modern Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra   +2 more
wiley   +1 more source

Cyclopropane: a vindication.

open access: yesSouth African medical journal = Suid-Afrikaanse tydskrif vir geneeskunde, 2003
Click on the link to view.
openaire   +2 more sources

Efficient Preparation of 2,3-Disubstituted Cyclopropane-1-Carbonitriles via Selective Decarboxylation of 1-Cyanocyclopropane-1-Carboxylates

open access: yes, 2017
2,3-Disubstituted cyclopropane-1-carbonitriles were efficiently formed via a selective decarboxylation reaction of substituted 2-aroyl-3-aryl-1-cyano-cyclopropane-1-carboxylates in up to 92% yield.
Lizhong Wang   +4 more
core   +1 more source

Metal‐Catalyzed Benzannulation: Recent Advances in Catalyst Design, Mechanistic Insights, and Aromatic Framework Construction

open access: yesThe Chemical Record, EarlyView.
This review offers a contemporary overview of metal‐catalyzed benzannulation (2018–present) encompassing transition, main‐group, post‐transition, and rare‐earth‐metal catalysts. It systematically highlights catalyst design, mechanistic insights, stereo‐ and regioselectivity, and synthetic applications toward aromatic and heteroaromatic scaffolds, while
Sana Jamshaid   +5 more
wiley   +1 more source

Synthesis of Aminocyclopropanes by Redox‐Neutral Aminoalkylation

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 45, 2 November 2026.
Aminocyclopropane synthesis by hydroaminoalkylation utilizing cheap, readily available starting materials is presented, offering orthogonality to commonly used methods and allowing broad functional‐group tolerance. Solvent‐mediated conditions enable the reaction of a pre‐formed hemiaminal with alkenes and alkynes.
Gwyndaf A. Oliver   +6 more
wiley   +1 more source

trans-2-(2,5-Dimethoxy-4-iodophenyl)cyclopropylamine and trans-2-(2,5-dimethoxy-4-bromophenyl)cyclopropylamine as potent agonists for the 5-HT2 receptor family

open access: yesBeilstein Journal of Organic Chemistry, 2012
A strategy to replace the ethylamine side chain of 2,5-dimethoxy-4-iodoamphetamine (DOI, 1a), and 2,5-dimethoxy-4-bromoamphetamine (DOB, 1b) with a cyclopropylamine moiety was successful in leading to compounds with high affinity at the 5-HT2 family of ...
Adam Pigott   +5 more
doaj   +1 more source

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