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Enantioselective intramolecular cyclopropanation via a cationic sulfoxonium-Rh-carbene. [PDF]

open access: yesNat Commun
Xing Y   +6 more
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Thermal imaging using sulfur polymer optics. [PDF]

open access: yesNat Commun
Tonkin SJ   +16 more
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“Cyclopropanation of Cyclopropanes”: GaCl3-Mediated Ionic Cyclopropanation of Donor–Acceptor Cyclopropanes with Diazo Esters as a Route to Tetrasubstituted Activated Cyclopropanes

The Journal of Organic Chemistry, 2021
A new ionic cyclopropanation process involving the addition of diazo esters to donor-acceptor cyclopropanes (DAC) activated by GaCl3 has been developed. The reactions occur via 1,2-zwitterionic gallium complexes with elimination of nitrogen in all cases to give 1,1,2,3-tetrasubstituted cyclopropanes as the main products.
Irina A. Borisova   +5 more
openaire   +2 more sources

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