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Photocatalytic Radical Functionalization of Alkenylammonium Salts. [PDF]

open access: yesPrecis Chem
Yoshita A   +4 more
europepmc   +1 more source

Direct Access to Iron Carbenes from Aldehyde, Ketone, and Formamide Feedstocks. [PDF]

open access: yesJ Am Chem Soc
Pedersen PS   +9 more
europepmc   +1 more source

A Rh(II) Catalyzed Atropisomer Selective Ring Expansion of 3-Aryl Indoles to 4-Aryl Quinolines. [PDF]

open access: yesACS Catal
Basilaia M   +7 more
europepmc   +1 more source
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“Cyclopropanation of Cyclopropanes”: GaCl3-Mediated Ionic Cyclopropanation of Donor–Acceptor Cyclopropanes with Diazo Esters as a Route to Tetrasubstituted Activated Cyclopropanes

The Journal of Organic Chemistry, 2021
A new ionic cyclopropanation process involving the addition of diazo esters to donor-acceptor cyclopropanes (DAC) activated by GaCl3 has been developed. The reactions occur via 1,2-zwitterionic gallium complexes with elimination of nitrogen in all cases to give 1,1,2,3-tetrasubstituted cyclopropanes as the main products.
Irina A. Borisova   +5 more
openaire   +2 more sources

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