Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs-Stoltz (Et<sub>3</sub>SiH/KO<i>t</i>Bu) conditions. [PDF]
Stewart AJ +10 more
europepmc +1 more source
Photocatalytic Radical Functionalization of Alkenylammonium Salts. [PDF]
Yoshita A +4 more
europepmc +1 more source
Direct Access to Iron Carbenes from Aldehyde, Ketone, and Formamide Feedstocks. [PDF]
Pedersen PS +9 more
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Structure-Function Relationships of Unusual Fatty Acids with Distinctive Functional Group Modifications and Carbon Chain Skeletons: Focus on the Roles of Double Bonds and Methyl Branches in Metabolism and Signaling. [PDF]
Li Y +6 more
europepmc +1 more source
A DFT Study on the Mechanism of Selective Formation of Substituted Azepines From 1-Azabutadienes and Cyclopropanes. [PDF]
Kobayashi R +5 more
europepmc +1 more source
A Rh(II) Catalyzed Atropisomer Selective Ring Expansion of 3-Aryl Indoles to 4-Aryl Quinolines. [PDF]
Basilaia M +7 more
europepmc +1 more source
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A new ionic cyclopropanation process involving the addition of diazo esters to donor-acceptor cyclopropanes (DAC) activated by GaCl3 has been developed. The reactions occur via 1,2-zwitterionic gallium complexes with elimination of nitrogen in all cases to give 1,1,2,3-tetrasubstituted cyclopropanes as the main products.
Irina A. Borisova +5 more
openaire +2 more sources

