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Demethylenation of Cyclopropanes via Photoinduced Guest-to-Host Electron Transfer in an M6 L4 Cage.
Angewandte Chemie, 2019Unusual demethylenation reactions of cyclopropanes under UV-light irradiation were found within a cavity of a photoactive coordination cage. The reaction proceeded via a guest-to-host electron transfer owing to the highly electron-deficient nature of the
W. Cullen, Hiroki Takezawa, M. Fujita
semanticscholar +1 more source
Imidazol-5-one as an Acceptor in Donor-Acceptor Cyclopropanes: Cycloaddition with Aldehydes.
Organic Letters, 2020Spiro[imidazol-5-one-4,1'-cyclopropanes] behave as donor-acceptor (D-A) cyclopropanes in a formal cycloaddition reaction with aldehydes. The activation of such type of cyclopropanes is achieved with an equivalent of Brønsted acid.
A. Mikhaylov +6 more
semanticscholar +1 more source
Cyclopropanes in organocatalytic transformations
, 2020Organocatalysis represents a powerful and reliable tool in modern organic chemistry. Cyclopropanes are a versatile compound class whose reactivity exceeds that of other cyclic hydrocarbons.
C. Apel, M. Christmann
semanticscholar +1 more source
Visible-Light-Mediated Synthesis of β-Chloro Ketones from Aryl Cyclopropanes.
Angewandte Chemie, 2019We report the visible-light-mediated synthesis of β-chloro ketones from aryl cyclopropanes, oxygen, hydrochloric acid, and nitric acid. The operationally simple and catalyst-free method uses cheap standard laboratory reagents and displays broad ...
D. Petzold +3 more
semanticscholar +1 more source
Metal-catalysed C–C bond formation at cyclopropanes
Nature Reviews Chemistry, 2023Alexis L. Gabbey +2 more
semanticscholar +1 more source
Journal of Organic Chemistry, 2019
The Lewis acid catalyzed ring opening reaction of Donor-Acceptor (D-A) cyclopropanes with alkyl hydroperoxides is reported to furnish various peroxycarbonyls and 1,3-haloperoxygenated compounds in good to excellent yields.
Kuldeep Singh +6 more
semanticscholar +1 more source
The Lewis acid catalyzed ring opening reaction of Donor-Acceptor (D-A) cyclopropanes with alkyl hydroperoxides is reported to furnish various peroxycarbonyls and 1,3-haloperoxygenated compounds in good to excellent yields.
Kuldeep Singh +6 more
semanticscholar +1 more source
AINS - Anästhesiologie · Intensivmedizin · Notfallmedizin · Schmerztherapie, 1995
H, Böhrer, M, Goerig
openaire +2 more sources
H, Böhrer, M, Goerig
openaire +2 more sources
Asymmetric Catalytic Reactions of Donor–Acceptor Cyclopropanes
Angewandte Chemie - International Edition, 2021Xiaohua Liu, Feng, Xiaoming, Yong Xia
exaly

