Results 21 to 30 of about 5,606 (188)
Kinetically Stable Boron‐Heteroatom Bonds
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova +8 more
wiley +2 more sources
Dative-nominative alterations in Germanic languages. A generative prespective
This paper focuses on the conditions under which dative–nominative alternations take place, mainly within the Germanic family, with a view to illuminate the nature of dative case cross-linguistically.
A. Alexiadou +2 more
doaj +1 more source
Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride
Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal‐bipyramidal aluminum center is analyzed, and the coordination chemistry and Al(I)Br transfer reactivity of the complexes are presented.
Charlotte S. V. Weiß +1 more
wiley +2 more sources
Latin datives with prefixed verbs and beyond: A view from the theory of applicatives
I discuss the syntax and semantics of dative DPs with a spatial (Ground) interpretation, focusing on those dependent on prefixed verbs, in Early and Classical Latin.
Víctor Acedo-Matellán
doaj +1 more source
T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag +4 more
wiley +2 more sources
Personal and impersonal sentences in Lithuanian and Proto-Indo-European
The dative subject construction of the historical languages is the continuation of the Proto-Indo-European thematic present. It was largely replaced by the construction with a nominative subject that continued the athematic present as well as the aorist,
Frederik Kortlandt
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Bond Length as a Unified Descriptor for Stable Iodine Battery
Charge transfer induced by the interactions between iodine and ligands leads to the elongation of the I–I bond. This resulting bond length correlates directly with coordination strength, serving as a unified descriptor for the rational design of both cathode hosts and electrolyte components.
Mengzi Geng +9 more
wiley +2 more sources
Under certain conditions, nonstandard varieties of Basque display so-called quirky dative objects, a phenomenon that belongs to the broader family of constructions studied in the typological literature as Differential Object Marking (DOM).
Beatriz Fernández, Milan Rezac
doaj +1 more source
The derivation of dative alternations [PDF]
This paper argues for an updated version of the classical derivational approach to Double Object Constructions and dative constructions across languages. We show that the arguments to postulate a non-derivational approach do not hold and that, in fact, such an approach runs into unsolvable problems. We argue that the structural alternation is triggered
Ormazabal Zamakona, Javier, Romero, Juan
openaire +2 more sources
The Dative Markers and Their Developments in Hunan Sinitic Languages
This study is based on a sample of 30 Sinitic languages spoken in the Hunan Province. Its first objective is to explore the types of dative markers, comparing the form of the dative with allative, passive, benefactive, and differential object markers in ...
Xinyi Gao
doaj +1 more source

