Results 41 to 50 of about 11,079 (227)
Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character
Angewandte Chemie, EarlyView.Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge +3 more
wiley +2 more sources
Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation
Angewandte Chemie, EarlyView.A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang +6 more
wiley +2 more sources
Advanced Materials, EarlyView.Harnessing the synergistic interplay of supramolecular self‐assembly, under macromolecular crowding conditions, and enzymatic‐mediated covalent crosslinking toward a stable protein‐based G‐quadruplex‐derived supramolecular bioink. This bioinspired strategy enables the biofabrication of complex and tunable ECM‐mimetic constructs, providing a platform ...
Vera Sousa +6 more
wiley +1 more source
Advanced Science, EarlyView.Gassorption analysis of in‐plane functionalized carbons reveals small, uniform ultramicropore signatures as potential artefacts of specific adsorption of the probe gases. Low‐pressure Langmuir fitting links these features to distinct functionalities via adsorption energies, enabling straightforward quantification of otherwise inaccessible surface‐site ...
Simon W. J. Dietzmann +9 more
wiley +1 more source
The Spray/Load and Dative Alternations: Aligning VP Structure and Contextual Effects. [PDF]
, 2016 The theoretical and experimental work presented in this thesis investigates the spray/load and dative alternations. The purpose is to provide a comprehensive analysis of the alternations in terms of their syntactic structures and to account for how ...
D'Elia, Samuel C
core
Reconsidering inalienable possession with definite determiners in French
Isogloss, 2022 In many Romance and Germanic languages, definite determiners can indicate possession for a subset of nouns that have often been called nouns of ‘inalienable’ possession. This paper addresses the question of why and how the definite determiner contributes
Johan Rooryck
doaj +1 more source
Dative (first) complements in Basque
Journal of Portuguese Linguistics, 2012 This article examines dative complements of unergative verbs in Basque, i.e., dative arguments of morphologically “transitive” verbs, which, unlike ditransitives, do not co-occur with a canonical object complement.
Beatriz Fernández, Jon Ortiz de Urbina
doaj +2 more sources
Dative shift in a language without dative? The (allative) case of Finnish [PDF]
Linguistics, 2014 Abstract Dative shift is a two-fold process that affects both the morphological coding and the order of T and R arguments of a three-participant construction, as in the teacher gave a book to the student vs. the teacher gave the student a book.
openaire +2 more sources
A further argument for a syncretic analysis of DOM and dative in Spanish
Topics in Linguistics, 2020 This paper offers an argument to analyse the Spanish form /a/ as a syncretic case marker for accusative differential object marking (dom) and dative. The literature on free relative clauses has established that syncretism allows the repair of feature ...
Pérez Carlos Muñoz
doaj +1 more source