Results 31 to 40 of about 57,576 (277)
Isolation and Reactivity of a Square‐Planar Trisamido Silane
Angewandte Chemie, EarlyView.We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel +5 more
wiley +2 more sources
Latin datives with prefixed verbs and beyond: A view from the theory of applicatives
Catalan Journal of Linguistics, 2017 I discuss the syntax and semantics of dative DPs with a spatial (Ground) interpretation, focusing on those dependent on prefixed verbs, in Early and Classical Latin.
Víctor Acedo-Matellán
doaj +1 more source
Bodily injuries and dative experiencers in Old Frisian [PDF]
, 2019 This article offers a descriptive account of body part constructions in Old East Frisian texts and analyzes the occurrence of dative experiencers in such clauses.
Bruno, Laura, Kerkhof, Peter Alexander
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Homoleptic and Heteroleptic Carbones L1‐C‐L2
Angewandte Chemie, EarlyView.DFT and CCSD(T) calculations reveal that heteroleptic carbones L₁–C–L2 are thermodynamically stable species even with a weakly binding donor such as N2. Bond strengths show no simple correlation with bond lengths. Weaker carbon‐ligand bonds in homoleptic complexes L1─C─L1 are mostly strengthened in heteroleptic carbons L1─C─L2, while stronger bonds L2 ...
Ya Hu +4 more
wiley +2 more sources
Discrete Entailment-Based Linking and -EE Nouns in English [PDF]
, 2007 Barker (1998) argues that since the referent of an -ee noun can be an indirect object, a direct object, a prepositional object, or a subject, -ee nouns cannot be described as a syntactic natural class.
González, Luis
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Structurally Constrained Stibenium: Metallomimetic C−Si Bond Activation
Angewandte Chemie, EarlyView.A structurally constrained stibenium cation supported by a 2,6‐bis(o‐carborano)pyridine pincer‐type ligand was prepared, and its preliminary reactivity toward silanes was investigated. Remarkably, Si−C bonds in silanes undergo activation via an oxidative‐addition‐type process at the cationic Sb center.
Donia Toami, Roman Dobrovetsky
wiley +2 more sources
Anuario del Seminario de Filología Vasca "Julio de Urquijo", 2010 Under certain conditions, nonstandard varieties of Basque display so-called quirky dative objects, a phenomenon that belongs to the broader family of constructions studied in the typological literature as Differential Object Marking (DOM).
Beatriz Fernández, Milan Rezac
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Personal and impersonal sentences in Lithuanian and Proto-Indo-European
Vilnius University Open Series, 2022 The dative subject construction of the historical languages is the continuation of the Proto-Indo-European thematic present. It was largely replaced by the construction with a nominative subject that continued the athematic present as well as the aorist,
Frederik Kortlandt
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The rise of ergativity in Hindi: assessing the role of grammaticalization [PDF]
, 2009 This article investigates the origins and development of the ergative patterning in Hindi. Following traditional Indo-Aryan scholarship, two evolutions are discerned: (i) the reanalysis of a passive as an ergative construction, and (ii) the development ...
De Cuypere, Ludovic, Verbeke, Saartje
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Homoleptic and Heteroleptic Borylones L1‐B(Ph)‐L2
Angewandte Chemie, EarlyView.Density functional theory and CCSD(T) calculations reveal that homoleptic and heteroleptic borylones L1–B(Ph)–L2 are thermodynamically accessible. Remarkably, the homoleptic borylones B(Ph)(N2)2 and B(Ph)(SPh2)2 exhibit higher bond dissociation energies than the related carbones.
Qin Ma +4 more
wiley +2 more sources