Results 131 to 140 of about 90,046 (287)

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Dual‐Stabilized Single‐Site Fe(II) for Catalytic Conversion of CO2 to Propiolic Acid Under Ambient Condition

EcoEnergy, EarlyView.
We develop a highly cost‐effective heterogeneous catalyst for efficient CO2 conversion to propiolic acid under mild conditions via a nano‐confined approach with porous MIL support. ABSTRACT Efficient conversion of carbon dioxide to organics has been a promising outlet for value‐added carbon dioxide consumption.
Bin Lei, Zhenzhen Zhou, Xiao Liu, Bo Li, Wenyuan Wang, Jian‐Gong Ma, Peng Cheng   +6 more
wiley   +1 more source

Recent Developments in Azomethine Ylide-Initiated Double Cycloadditions

Molecules
Azomethine ylides (AMYs) have a nitrogen–carbon double bond and an electron lone pair on the nitrogen atom. They are essential 1,3-dipoles for [3+2] cycloadditions in the synthesis of pyrrolidine-containing heterocycles.
Tieli Zhou, Xiaofeng Zhang, Yan Jan Sheng, Desheng Zhan, Wei Zhang   +4 more
doaj   +1 more source

Optimally Carbonized Mangrove Wood–Derived Hard Carbon with a Soft Carbon Coating for High‐Performance Sodium‐Ion Battery Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
High‐performance SIB anodes are developed using mangrove wood–derived hard carbon, optimized through controlled carbonization temperatures and pitch‐derived soft carbon coatings. The resulting PC‐10 composite achieves a superior reversible capacity of 297.5 mAh g−1 and an 82% ICE by suppressing irreversible reactions and enhancing interfacial stability
Hyung‐Keun Shin, Gyoo‐Rin Kim, Seong‐Ju Han, Jeong Mi Yeon, Hyun‐Kyung Kim   +4 more
wiley   +1 more source

Enhanced Photocatalytic Antibiotic Micropollutants Removal Resulting From a Synergism Between Cu Single Atoms and Carbon Vacancies on Graphitic Carbon Nitride

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Scheme of the synergistic degradation for antibiotic micropollutants in the Cu/ag‐C3N4 system. Photocatalytic processes driven by visible‐light irradiation offer a sustainable means of micropollutants removal from aquatic environments without the addition of reagents.
Xiaozhe Song, Cong Yan, Qinghua Yan, Congzhe Ren, Xin Liu, Ruiyan Zhang, Lei Chen, Chongqing Xu, Zhouyang Long, Wenyu Wang, Mingming Song, Xiaoguo Shi, Hui Wang   +12 more
wiley   +1 more source

The Correlation between Amino Acids and Biogenic Amines in Wines without Added Sulfur Dioxide

Fermentation
In classical methods of wine production, amino acids play a critical role, as they are fundamental to all types of fermentation. Beyond their consumption in fermentative processes, amino acids undergo several transformations, such as decarboxylation ...
Sorin Macoviciuc, Marius Niculaua, Constantin-Bogdan Nechita, Bogdan-Ionel Cioroiu, Valeriu V. Cotea   +4 more
doaj   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

European Journal of Inorganic Chemistry, EarlyView.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa, Hiroe Fukuzaki, Nana Aizawa, Sho Ikeda, Airi Kawabe, Saori Nishiyama, Iori Nagasawa, Masaya Okamura, Shiro Hikichi   +8 more
wiley   +1 more source

Possible atmospheric lifetimes and chemical reaction mechanisms for selected HCFCs, HFCs, CH3CCl3, and their degradation products against dissolution and/or degradation in seawater and cloudwater [PDF]

For a wide variety of atmospheric species including CO2, HNO3, and SO2, dissolution in seawater or cloudwater followed by hydrolysis or chemical reaction represents a primary pathway for removal from the atmosphere.
Chameides, W. L., Wine, P. H.
core   +1 more source

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

European Journal of Organic Chemistry, EarlyView.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer, Jun Fang, Chonghuo Liu, Guillaume Lefèvre, Gérard Guillamot, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +6 more
wiley   +1 more source

Decarboxylation-Driven Double Annulations: Innovative Multi-Component Reaction Pathways

Molecules
A concerted five-component reaction strategy has been developed, featuring double [3+2] cycloadditions utilizing aspartic acid. This approach provides valuable insights into mechanistic pathways, allowing for the distinction between concerted and ...
Desheng Zhan, Gang Yang, Tieli Zhou, Sashirekha Nallapati, Xiaofeng Zhang   +4 more
doaj   +1 more source