Results 131 to 140 of about 81,314 (317)
Decarboxylation of Substituted Sodium Phenylpropiolates
, 1961 The kinetics of the thermal decarboxylation of a series of substituted sodium phenylpropiolates were studied in detail. The reaction proceeded without formation of significant amounts of side products: its rate was independent of hydrogen ion ...
Wong, Edward
core +1 more source
Chemistry – A European Journal, EarlyView.Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley +1 more source
The Correlation between Amino Acids and Biogenic Amines in Wines without Added Sulfur Dioxide
FermentationIn classical methods of wine production, amino acids play a critical role, as they are fundamental to all types of fermentation. Beyond their consumption in fermentative processes, amino acids undergo several transformations, such as decarboxylation ...
Sorin Macoviciuc +4 more
doaj +1 more source
Parameters Governing Ruthenium Sawhorse-Based Decarboxylation of Oleic Acid
, 2017 Ruthenium-catalyzed decarboxylation of 9-cis-octadecenoic is a path to produce biobased olefins. Here, a mechanistic study of this reaction was undertaken utilizing a closed reaction system and a pressure reactor.
Rex E. Murray (3681940) +6 more
core +1 more source
Chemistry – A European Journal, EarlyView.Starting from carboxylic acids and Selectfluor‐derivatives, functionalized diazabicyclooctanes can be obtained via a novel Polonovski‐type rearrangement proceeding under mild reaction conditions. Besides their use in organic synthesis the unique structure and reactivity of the rearrangement products enables applications in medicinal chemistry ...
Jakob Kuhn +5 more
wiley +1 more source
Decarboxylative photocatalytic transformations
Chemical Society ReviewsPhotocatalytic decarboxylation of carboxylic acids or their redox active esters has become an important strategy in organic chemistry.
Francisco Foubelo +5 more
openaire +2 more sources
Chemistry – A European Journal, EarlyView.Manganese oxides (MnOX) of different structures and with different Mn oxidation states exhibit significant variation in their reactivity toward the oxidation of allylic alcohols. Using two allylic alcohol model substrates, we demonstrate the relationship between activity and MnOX structure, Mn4+ content and incorporated secondary cations.
Erdogan Kasisari +6 more
wiley +1 more source
Decarboxylation-Driven Double Annulations: Innovative Multi-Component Reaction Pathways
MoleculesA concerted five-component reaction strategy has been developed, featuring double [3+2] cycloadditions utilizing aspartic acid. This approach provides valuable insights into mechanistic pathways, allowing for the distinction between concerted and ...
Desheng Zhan +4 more
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Chemistry – A European Journal, EarlyView.Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik +11 more
wiley +1 more source
Beilstein Journal of Organic ChemistryThis review focuses on new directions in (3 + 2) cycloaddition of azomethine ylides to alkenes, resulting in the formation of fused or spiro-fused pyrrolidine derivatives with multiple chiral centers under high regio- and stereocontrol.
Ekaterina V. Berezhnaya +3 more
doaj +1 more source