Results 131 to 140 of about 51,237 (293)

Development of a Catalytic Aromatic Decarboxylation Reaction

open access: yes, 2016
A palladium-catalyzed aromatic decarboxylation reaction has been developed. With electron-rich aromatic acids, the reaction proceeds efficiently under fairly mild conditions in good yields.
Barbara J. Morgan (2328628)   +4 more
core   +1 more source

Synthesis of 2‐Aza‐Bicyclo[4.3.0]nonane Derivatives Related to the Camporidines via Intramolecular [3+2]‐Cycloaddition

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The intramolecular nitrile oxide olefin [3 + 2]‐cycloaddition offers a reliable entry toward 2‐aza‐bicyclo[4.3.0]‐nonanes, a substructure found in several bioactive piperidine alkaloids. The required oxime precursors were prepared in non‐racemic form by Ir‐catalyzed asymmetric allylation and ring‐closing metathesis.
Alicia Köcher   +5 more
wiley   +1 more source

Decarboxylation and deterioration reaction of cashew nut shell liquid [PDF]

open access: yes
วิทยานิพนธ์ (วศ.ม.)--จุฬาลงกรณ์มหาวิทยาลัย, 2543น้ำมันเปลือกเมล็ดมะม่วงหิมพานต์ (CNSL) เป็นวัตถุดิบทางธรรมชาติที่สามารถนำมาทำเป็นผลิตภัณฑ์พอลิเมอร์ที่มีประโยชน์ได้หลายชนิด เช่น ผ้าเบรกหรือวาณิชเป็นต้น ก่อนนำมาใช้งาน CNSL ควรได้รับการปรับปรุงคุณภาพเบื้องต้
มโน ลิ่มวรพันธุ์
core  

Gold(I)‐Mediated Reactivity of Allenes With Mesoionic Nucleophiles: A Computational Exploration

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The regioselective gold(I)‐mediated reactivity of allenes with mesoionic nucleophiles has been evaluated through computational analysis of the mechanisms involved. Instead of typical (3 + 2) pathways, sydnones and münchnones favour the formal (3 + 3) cyclizations affording substituted dihydropyridines.
Eduardo Garcia‐Padilla, Feliu Maseras
wiley   +1 more source

The Catalysed Decarboxylation of Oxaloacetic Acid [PDF]

open access: yes, 1959
The nature of the chelate compounds formed by transition metal ions with oxaloacetic acid in aqueous solution, has been investigated spectrophotometrically and potentiometrically. The mechanism of the catalysed reaction has been clarified.
Hay, Robert W
core  

Pyruvate dehydrogenase autoantibodies in autoantibody‐negative patients with seizures are associated with reduced pyruvate dehydrogenase activity

open access: yesEpilepsia, EarlyView.
Abstract Objective We investigated the presence and potential functional relevance of antimitochondrial autoantibodies in patients suspicious for autoimmune encephalitis (AIE) associated with psychiatric symptoms and/or seizures, who were negative for known antineuronal autoantibodies.
Annika Breuer   +12 more
wiley   +1 more source

The gold(I)-catalysed protodecarboxylation mechanism

open access: yes, 2015
The authors thank the EPSRC and the ERC (FUNCAT) for funding. S.P.N. is a Royal Society Wolfson Merit Award holder.A mechanistic study of the gold-catalysed protodecarboxylation is described.
Nolan, Steven Patrick   +4 more
core   +1 more source

Characterization of Cantaloupe, Grape, Pumpkin, and Tomato Seed Oils From Xinjiang: Oxidative Stability, Volatile‐Compound Analysis, and Sensory Evaluation

open access: yesFood Chemistry International, EarlyView.
This study compares oxidative stability, fatty acid profiles, volatile compounds, and sensory attributes of four Xinjiang seed oils. Distinct aldehyde‐driven aroma patterns and compositional differences were revealed, providing a scientific basis for quality evaluation and valorization of underutilized plant seed oils in food applications.
Yilai Wan   +4 more
wiley   +1 more source

Effects of high‐moisture extrusion processing on reducing anti‐nutritional factors and allergenicity in plant‐based materials—A mini review

open access: yesFood Biomacromolecules, EarlyView.
Abstract The rising demand for plant‐based meat alternatives has had advancements in processing technologies such as extrusion to meet consumer preferences for enhanced sensory qualities and nutritional benefits. High moisture extrusion (HME), a thermo‐mechanical process employing elevated moisture levels (40%–70%), has emerged as a promising method ...
Nur Hameedah Binte Ramadhan   +2 more
wiley   +1 more source

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