Results 141 to 150 of about 81,314 (317)

Rhodium‐Catalyzed Synthesis of Enantioenriched α‐Substituted Primary Amines Through Asymmetric Transfer Hydrogenation

open access: yesChemistry – A European Journal, EarlyView.
Enantioenriched α‐substituted primary amines are efficiently prepared by rhodium‐catalyzed asymmetric transfer hydrogenation of ortho‐hydroxyaryl N─H imines under mild conditions using a low catalyst loading and ammonium formate as the hydrogen source in high yields (up to 99%) and enantioselectivities (up to 99% ee).
Chonghuo Liu   +4 more
wiley   +1 more source

Near‐White Circularly Polarized Luminescence by Color Mixing Utilizing Surface‐Fluorophore‐Modified Cellulose Nanocrystals in Composite Films

open access: yesChemistry – A European Journal, EarlyView.
Robust, bio‐derived, and freestanding films based on cellulose nanocrystals (CNCs), covalently decorated with achiral fluorophores, transduce shape chirality and supramolecular helicity into near‐white circularly polarized luminescence (CPL). With composites covering the visible spectrum, near‐white, right‐handed CPL with high luminescence dissymmetry (
Asmita Shah   +10 more
wiley   +1 more source

Oxidative decarboxylation of glucuronosides and the synthesis of xylitol

open access: yes, 2004
The purpose of this research was to develop a novel chemical synthesis of xylitol, which could potentially be implemented on an industrial scale. Principally, the oxidative decarboxylation of glucuronosides was pursued as a novel route to yield xylitol ...
Stapley, Jonathan A
core   +1 more source

Microwave‐assisted catalytic pyrolysis of textile wastes: Synergistic effects and product characteristics

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study examines the microwave‐assisted catalytic pyrolysis (MACP) of individual and blended textiles (cotton, polyester, nylon 6) using ZnO and a ZnO/natural zeolite catalyst. In a custom‐built microwave reactor operated at 500°C, 1 kW power, and a 15‐min residence time, textile wastes were pyrolyzed.
Peyman Alizadeh   +3 more
wiley   +1 more source

Hydrogen donor‐assisted visbreaking of Canadian oil sands bitumen

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract High‐viscosity Canadian oil sands bitumen requires processing for efficient transportation and refining. Partial upgrading technologies, primarily based on thermal processing, can effectively reduce, or even eliminate, the use of costly diluent, increase bitumen quality and market value, potentially decrease greenhouse gas (GHG) emissions, and
Yi Zhang, Mohamed Ali, Jinwen Chen
wiley   +1 more source

Catalytic Hydrothermal Liquefaction of Polyethylene With Pt/C to Tune Product Selectivity

open access: yesCleanMat, EarlyView.
Pt/C‐catalyzed hydrothermal liquefaction of polyethylene in supercritical water enables time‐dependent control of product selectivity, producing paraffin‐rich oils at shorter reaction times and aromatic‐enriched products at longer times without external hydrogen. ABSTRACT Hydrothermal liquefaction (HTL) represents a promising thermochemical pathway for
Taofeng Lu, Wan‐Ting Chen
wiley   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

An Investigation Into the Yields of 3,4‐Methylenedioxyphenyl‐2‐propanone (MDP2P) From Glycidate Pre‐Precursors

open access: yesDrug Testing and Analysis, EarlyView.
Hydrolysis of the glycidate pre‐precursors MMDMG and EMDMG was evaluated for MDP2P production. Acid hydrolysis of MMDMG (HCl, 100°C, 18 h) yielded the highest MDP2P recovery (79%), whereas base hydrolysis produced only slightly lower yields (73%), demonstrating both pathways are effective routes to this key MDMA precursor.
Alexandra L. Mercieca   +4 more
wiley   +1 more source

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