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Direct reversible decarboxylation from stable organic acids in dimethylformamide solution
Science, 2020Simple swaps of CO2 The loss of carbon dioxide (CO2) from carboxylic acids is a common reaction in both biochemical and synthetic contexts, but it has generally involved catalysis or prolonged heating. Kong et al.
D. Kong +4 more
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Cannabinoid Decarboxylation: A Comparative Kinetic Study
Industrial & Engineering Chemistry Research, 2020Cannabinoids like Δ9-tetrahydrocannabinol (THC), cannabidiol (CBD), and cannabigerol (CBG) are considered the main active components in Cannabis sativa L.
T. Moreno, P. Dyer, S. Tallon
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Catalytic Hydrothermal Decarboxylation and Cracking of Fatty Acids and Lipids over Ru/C
ACS Sustainable Chemistry and Engineering, 2019Here, we report on the catalytic hydrothermal conversion of fatty acids and lipids to a range of hydrocarbons using Ru/C without the need for addition of external H2 supplies.
Jing Zhang +3 more
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Decarboxylation Cross-Linking of Triptycene-Based Tröger’s Base Polymers for Gas Separation
, 2020Previous studies demonstrate that decarboxylation crosslinking improves both the plasticization resistance and gas separation properties of a polymer precursor.
Tong Zhang, Liming Deng, Pei Li
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Nature, 1953
INVESTIGATIONS in this department into the nature of the chrome tanning process have involved the preparation of various modified forms of collagen. Among possible modifications, the decarboxylation of collagen appeared to be of interest, although it has received scant attention from previous workers.
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INVESTIGATIONS in this department into the nature of the chrome tanning process have involved the preparation of various modified forms of collagen. Among possible modifications, the decarboxylation of collagen appeared to be of interest, although it has received scant attention from previous workers.
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Nonenzymatic decarboxylation of pyruvate
Analytical Biochemistry, 1984Triton X-100, retinol, retinoic acid, retinal, hexane, dithiothreitol, mercaptoethanol, and some other commercially available chemicals caused nonenzymatic decarboxylation of pyruvate and alpha-ketoglutarate. "Lipids" obtained from human or pigeon liver homogenates using isopropanol/hexane also had very high nonenzymatic decarboxylating activity on ...
G, Constantopoulos, J A, Barranger
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The Decarboxylative Blaise Reaction
The Journal of Organic Chemistry, 2007Reaction of aryl nitriles with potassium ethyl malonate in the presence of zinc chloride and a catalytic amount of Hünig's base provided beta-amino acrylates in moderate to good yield. Compared to the classical Blaise reaction, this reaction is safer (endothermic), devoid of lacrimatory reagent, and is possible with 0.5-1.0 equiv of zinc chloride.
Jae Hoon, Lee +6 more
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Decarboxylation of Oxalacetate by Blood
Nature, 1948EVOLUTION of carbon dioxide from oxalacetate by washed rabbit erythrocytes at pH 7·4 has been reported previously1. Because of the solubility of carbon dioxide at that pH, this could at best be only a qualitative indication of the decarboxylation. Working in either phosphate or 2M acetate buffer, and measuring carbon dioxide formation by the standard ...
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