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The Decarboxylative Blaise Reaction
The Journal of Organic Chemistry, 2007Reaction of aryl nitriles with potassium ethyl malonate in the presence of zinc chloride and a catalytic amount of Hünig's base provided beta-amino acrylates in moderate to good yield. Compared to the classical Blaise reaction, this reaction is safer (endothermic), devoid of lacrimatory reagent, and is possible with 0.5-1.0 equiv of zinc chloride.
Jae Hoon, Lee +6 more
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Decarboxylation of Oxalacetate by Blood
Nature, 1948EVOLUTION of carbon dioxide from oxalacetate by washed rabbit erythrocytes at pH 7·4 has been reported previously1. Because of the solubility of carbon dioxide at that pH, this could at best be only a qualitative indication of the decarboxylation. Working in either phosphate or 2M acetate buffer, and measuring carbon dioxide formation by the standard ...
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Advances in Catalytic Decarboxylation of Bioderived Fatty Acids to Diesel-Range Alkanes
Renewable and Sustainable Energy Reviews, 2022Wuyuan Zhang, Bi-Shuang Chen, Lan Liu
exaly
Biocatalytic Asymmetric Decarboxylation
1999Biocatalytic decarboxylation is a unique reaction, in the sense that it can be considered to be a protonation reaction to a "carbanion equivalent" intermediate in aqueous medium. Thus, if optically active compounds can be prepared via this type of reaction, it would be a very characteristic biotransformation, as compared to ordinary organic reactions ...
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