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Oxidative decarboxylation of naproxen
Journal of Pharmaceutical Sciences, 1992The decarboxylation of naproxen (1H) and its salt (1-) was achieved by means of chemical [Ce(IV) or S2O8(2-)] and electrochemical oxidation. The product patterns were compatible with mechanisms involving single-electron transfer from the pi-system or the carboxylate moiety.
F, Boscá +5 more
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Nonenzymatic decarboxylation of pyruvate
Analytical Biochemistry, 1984Triton X-100, retinol, retinoic acid, retinal, hexane, dithiothreitol, mercaptoethanol, and some other commercially available chemicals caused nonenzymatic decarboxylation of pyruvate and alpha-ketoglutarate. "Lipids" obtained from human or pigeon liver homogenates using isopropanol/hexane also had very high nonenzymatic decarboxylating activity on ...
G, Constantopoulos, J A, Barranger
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The Decarboxylative Blaise Reaction
The Journal of Organic Chemistry, 2007Reaction of aryl nitriles with potassium ethyl malonate in the presence of zinc chloride and a catalytic amount of Hünig's base provided beta-amino acrylates in moderate to good yield. Compared to the classical Blaise reaction, this reaction is safer (endothermic), devoid of lacrimatory reagent, and is possible with 0.5-1.0 equiv of zinc chloride.
Jae Hoon, Lee +6 more
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Decarboxylation of Oxalacetate by Blood
Nature, 1948EVOLUTION of carbon dioxide from oxalacetate by washed rabbit erythrocytes at pH 7·4 has been reported previously1. Because of the solubility of carbon dioxide at that pH, this could at best be only a qualitative indication of the decarboxylation. Working in either phosphate or 2M acetate buffer, and measuring carbon dioxide formation by the standard ...
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Advances in catalytic decarboxylation of bioderived fatty acids to diesel-range alkanes
Renewable and Sustainable Energy Reviews, 2022Bi-Shuang Chen, Lan Liu, Rafael Luque
exaly

