Results 321 to 330 of about 111,262 (332)

Photocatalytic decarboxylation of lactic acid by Pt/TiO2.

Chemical Communications, 2016
A photocatalytic route for the conversion of lactic acid to acetaldehyde in water is demonstrated. Direct UV photolysis of lactic acid yields CO2 and ethanol via a radical mechanism.
Kaituo Liu, A. Litke, Yaqiong Su, Bart G van Campenhout, E. Pidko, E. Hensen   +5 more
semanticscholar   +1 more source

Biobased Methacrylic Acid via Selective Catalytic Decarboxylation of Itaconic Acid

, 2017
We report a biobased route to methacrylic acid via selective decarboxylation of itaconic acid utilizing catalytic ruthenium carbonyl propionate in an aqueous solvent system.
James C. Lansing, R. Murray, B. Moser
semanticscholar   +1 more source

Decarboxylation of fatty acids to terminal alkenes by cytochrome P450 compound I.

Journal of the American Chemical Society, 2015
OleT(JE), a cytochrome P450, catalyzes the conversion of fatty acids to terminal alkenes using hydrogen peroxide as a cosubstrate. Analytical studies with an eicosanoic acid substrate show that the enzyme predominantly generates nonadecene and that ...
J. Grant, Chun H. Hsieh, T. Makris
semanticscholar   +1 more source

Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation.

Organic Letters, 2016
An efficient copper-catalyzed trifluoromethylation of polysubstituted alkenes assisted by decarboxylation of β,γ-unsaturated carboxylic acids has been achieved.
Zhengbiao He, Ping Tan, Jinbo Hu
semanticscholar   +1 more source

Gas phase studies of the Pesci decarboxylation reaction: synthesis, structure, and unimolecular and bimolecular reactivity of organometallic ions.

Accounts of Chemical Research, 2015
CONSPECTUS: Decarboxylation chemistry has a rich history, and in more recent times, it has been recruited in the quest to develop cheaper, cleaner, and more efficient bond-coupling reactions.
R. O’Hair, Nicole J. Rijs
semanticscholar   +1 more source

Enhanced photocatalytic alkane production from fatty acid decarboxylation via inhibition of radical oligomerization

Nature Catalysis, 2020
Zhipeng Huang, Zhitong Zhao, Chaofeng Zhang, Jianmin Lu, Huifang Liu, Nengchao Luo, Jian Zhang, Feng Wang   +7 more
semanticscholar   +1 more source

Photobiocatalytic decarboxylation for olefin synthesis.

Chemical Communications, 2015
Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes.
Ioannis Zachos, S. K. Gaßmeyer, D. Bauer, V. Sieber, F. Hollmann, R. Kourist   +5 more
semanticscholar   +1 more source

Using CS2 to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes

, 2016
The reaction of the formate complex {2,6-(R2PO)2C6H3}Ni(OCHO) (R = tBu, 5; R = iPr, 6) with CS2 shows first-order kinetics in nickel concentration and zero-order in [CS2] when CS2 is used in large excess.
Q. Ma, Ting Liu, Anubendu Adhikary, Jie Zhang, J. Krause, Hairong Guan   +5 more
semanticscholar   +1 more source

Decarboxylation of Oleic Acid to Heptadecane over Pt Supported on Zeolite 5A Beads

, 2015
The synthesis of Pt supported on zeolite 5A beads for the decarboxylation of oleic acid to heptadecane is demonstrated. The use of a microporous ZIF-67 crystalline layer on zeolite 5A beads not only improved the heptadecane selectivity but also, most ...
Liqiu Yang, Kirby L. Tate, J. Jasinski, Moises A. Carreon   +3 more
semanticscholar   +1 more source

Decarboxylation of oleic acid over Pt catalysts supported on small-pore zeolites and hydrotalcite

, 2015
The catalytic decarboxylation and further conversions of oleic acid to paraffins, branched and aromatic hydrocarbons over Pt supported on small pore zeolites and hydrotalcite are demonstrated.
M. Ahmadi, Apolo Nambo, J. Jasinski, P. Ratnasamy, Moises A. Carreon   +4 more
semanticscholar   +1 more source