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Catalytic Hydrothermal Decarboxylation and Cracking of Fatty Acids and Lipids over Ru/C
ACS Sustainable Chemistry and Engineering, 2019Here, we report on the catalytic hydrothermal conversion of fatty acids and lipids to a range of hydrocarbons using Ru/C without the need for addition of external H2 supplies.
Jing Zhang +3 more
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Decarboxylation Cross-Linking of Triptycene-Based Tröger’s Base Polymers for Gas Separation
, 2020Previous studies demonstrate that decarboxylation crosslinking improves both the plasticization resistance and gas separation properties of a polymer precursor.
Tong Zhang, Liming Deng, Pei Li
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Organic Letters, 2019
A new method for 3-formalytion of indoles has been developed through electrochemical decarboxylation of glyoxylic acid with the amine as a dual function organocatalyst.
Dian‐Zhao Lin, Jing‐Mei Huang
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A new method for 3-formalytion of indoles has been developed through electrochemical decarboxylation of glyoxylic acid with the amine as a dual function organocatalyst.
Dian‐Zhao Lin, Jing‐Mei Huang
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Multicomponent decarboxylative allylations
Chem. Commun., 2014The reaction of Meldrum's acid, pyrrolide, and allyl carbonates allows a multicomponent decarboxylative coupling to form allylated acyl pyrroles. This strategy is made possible by the in situ formation of β-oxo carboxylates from Meldrum's acid. Subsequent decarboxylative enolate formation and electrophilic allylation complete the reaction.
Yamuna, Ariyarathna, Jon A, Tunge
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Pd-Catalyzed Decarboxylative Sonogashira Reaction via Decarboxylative Bromination
Organic Letters, 2018The decarboxylative alkynylation of (hetero)aryl carboxylic acids with terminal alkynes has been achieved by using a Pd(PPh3)4/PCy3 catalyst. This Pd-catalyzed method exhibits good functional group tolerance for both coupling partners and enables chemical modification of complex molecules. The establishment of this decarboxylative alkynylation reaction
Quandi Jiang +4 more
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Nature, 1953
INVESTIGATIONS in this department into the nature of the chrome tanning process have involved the preparation of various modified forms of collagen. Among possible modifications, the decarboxylation of collagen appeared to be of interest, although it has received scant attention from previous workers.
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INVESTIGATIONS in this department into the nature of the chrome tanning process have involved the preparation of various modified forms of collagen. Among possible modifications, the decarboxylation of collagen appeared to be of interest, although it has received scant attention from previous workers.
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Biocatalytic Asymmetric Decarboxylation
1999Biocatalytic decarboxylation is a unique reaction, in the sense that it can be considered to be a protonation reaction to a "carbanion equivalent" intermediate in aqueous medium. Thus, if optically active compounds can be prepared via this type of reaction, it would be a very characteristic biotransformation, as compared to ordinary organic reactions ...
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