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Electrochemistry in Deep Eutectic Solvents
The Journal of Physical Chemistry B, 2007We report the cyclic voltammetry, chronoamperometry, and scanning electrochemical microscopy of ferrocene dissolved in deep eutectic solvents (DES), consisting of choline chloride (ChCl) and either trifluoroacetamide (TFA) or malonic acid as the hydrogen-bond donor.
Chiemela A, Nkuku, Robert J, LeSuer
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Amphiphilically Nanostructured Deep Eutectic Solvents
The Journal of Physical Chemistry Letters, 2018Deep eutectic solvents (DESs) are neoteric liquids produced by mixing a high-melting-point salt and a molecular hydrogen-bond donor. Amphiphilic (self-assembled) liquid nanostructure, which is key for many of the useful properties of the related ionic liquid class, has not previously been experimentally demonstrated in DESs.
Samila McDonald +4 more
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Deep Eutectic Solvents for Biotechnology Applications
Biochemistry (Moscow), 2023Deep eutectic solvents (DESs) are an alternative to traditional organic solvents and ionic liquids and meet the requirements of "green" chemistry. They are easy to prepare using low-cost constituents, are non-toxic and biodegradable. The review analyzes literature on the use of DES in various fields of biotechnology, provides data on the types of DESs,
Olga V, Morozova +4 more
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Hydrophobic Deep Eutectic Solvents
2020Hydrophobic deep eutectic solvents combine the typical, desirable features of deep eutectic solvents; inexpensive, benign, often naturally occurring components with high hydrogen bond-forming tendencies with hydrophobicity; and the ability to form biphases with water. This implies an intrinsically challenging design, where hydrophobicity is obtained in
Byrne, Emily L. +4 more
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Water absorption by deep eutectic solvents
Physical Chemistry Chemical Physics, 2019Deep eutectic solvents are found to be highly hygroscopic when exposed to the atmosphere.
Yu Chen +4 more
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Charge Spreading in Deep Eutectic Solvents
ChemPhysChem, 2016AbstractAb initio molecular dynamic simulations reveal significantly reduced ion charges in several choline‐based deep eutectic solvents, which are cheap and eco‐friendly alternatives to ionic liquids. Increasing hydrogen bond strength between the anion and the organic compound enhances charge spreading from the anion to the organic compound while the ...
Stefan Zahn +2 more
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Deep Eutectic Solvents as Efficient Solvents in Biocatalysis
Trends in Biotechnology, 2019'Ideal' solvents in biocatalysis have to fulfill a large number of requirements, such as high substrate solubility, high enzyme activity and stability, and positive effects on reaction equilibrium. In the past decades, many enzymatic synthesis routes in water-based and nonaqueous (organic solvents, ionic or supercritical fluids) reaction media have ...
Pätzold, M. +5 more
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Strong Microheterogeneity in Novel Deep Eutectic Solvents
ChemPhysChem, 2019AbstractWith the increasing application of template assisted syntheses in deep eutectic solvents and successful application of hydrophobic deep eutectic solvents in extraction processes, where microheterogeneity plays a major role, suggestions for novel deep eutectic solvents which exhibit strong microheterogeneity are desirable.
Alizadeh, Vahideh +5 more
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Intrinsically Electrochromic Deep Eutectic Solvents
ChemistrySelect, 2019Abstract Multi‐colored intrinsically electrochromic based Deep Eutectic Solvents (IEDES) have been firstly developed. IEDES composed by the suitable mixing between viologen salt derivatives as HBA and ethylene glycol (EG), glycerol (Gly) and poly(ethylene glycol) (PEG) as ...
Hugo Cruz +4 more
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