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Electrochemistry in Deep Eutectic Solvents
The Journal of Physical Chemistry B, 2007We report the cyclic voltammetry, chronoamperometry, and scanning electrochemical microscopy of ferrocene dissolved in deep eutectic solvents (DES), consisting of choline chloride (ChCl) and either trifluoroacetamide (TFA) or malonic acid as the hydrogen-bond donor.
Chiemela A, Nkuku, Robert J, LeSuer
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Deep Eutectic Solvents as Efficient Solvents in Biocatalysis
Trends in Biotechnology, 2019'Ideal' solvents in biocatalysis have to fulfill a large number of requirements, such as high substrate solubility, high enzyme activity and stability, and positive effects on reaction equilibrium. In the past decades, many enzymatic synthesis routes in water-based and nonaqueous (organic solvents, ionic or supercritical fluids) reaction media have ...
Pätzold, M. +5 more
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Deep Eutectic Solvents for Biotechnology Applications
Biochemistry (Moscow), 2023Deep eutectic solvents (DESs) are an alternative to traditional organic solvents and ionic liquids and meet the requirements of "green" chemistry. They are easy to prepare using low-cost constituents, are non-toxic and biodegradable. The review analyzes literature on the use of DES in various fields of biotechnology, provides data on the types of DESs,
Olga V, Morozova +4 more
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Amphiphilically Nanostructured Deep Eutectic Solvents
The Journal of Physical Chemistry Letters, 2018Deep eutectic solvents (DESs) are neoteric liquids produced by mixing a high-melting-point salt and a molecular hydrogen-bond donor. Amphiphilic (self-assembled) liquid nanostructure, which is key for many of the useful properties of the related ionic liquid class, has not previously been experimentally demonstrated in DESs.
Samila McDonald +4 more
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Ferrier reaction in a deep eutectic solvent
Carbohydrate Research, 2015A mild and efficient synthesis of 2,3-unsaturated sugar derivatives has been achieved by conducting the Ferrier reaction in a deep eutectic solvent (DES). A wide range of alcohols including primary, secondary, benzylic, and sugar-derived primary alcohols can be used. Advantages include good yields, shorter reaction times and recyclability of DES.
Sunil M. Rokade, Prakash M. Bhate
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Water absorption by deep eutectic solvents
Physical Chemistry Chemical Physics, 2019Deep eutectic solvents are found to be highly hygroscopic when exposed to the atmosphere.
Yu Chen +4 more
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Charge Spreading in Deep Eutectic Solvents
ChemPhysChem, 2016AbstractAb initio molecular dynamic simulations reveal significantly reduced ion charges in several choline‐based deep eutectic solvents, which are cheap and eco‐friendly alternatives to ionic liquids. Increasing hydrogen bond strength between the anion and the organic compound enhances charge spreading from the anion to the organic compound while the ...
Stefan Zahn +2 more
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Natural Deep Eutectic Solvents – Solvents for the 21st Century
ACS Sustainable Chemistry & Engineering, 2014Green technology actively seeks new solvents to replace common organic solvents that present inherent toxicity and have high volatility, leading to evaporation of volatile organic compounds to the atmosphere. Over the past two decades, ionic liquids (ILs) have gained enormous attention from the scientific community, and the number of reported articles ...
Alexandre Paiva +5 more
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