Results 101 to 110 of about 39,740 (295)

Measuring Local Exothermic Effects During the Oxidative Coupling of Methane Using Operando Luminescence Thermometry

open access: yesAngewandte Chemie, EarlyView.
Operando luminescence thermometry shows that the local catalyst temperature can exceed the set oven temperature by almost 250°C during the exothermic oxidative coupling of methane process. We demonstrate how the reactor dimensions, catalyst grain size, and reactant feed mixture affect the local temperature.
Daniël W. Groefsema   +5 more
wiley   +2 more sources

MgO-supported Cu nanoparticles for efficient transfer dehydrogenation of primary aliphatic alcohols

open access: yes, 2009
Basic MgO-supported Cu nanoparticles showed exceptionally high activity for transfer dehydrogenation of 1-octanol and the yield of 1-octanal was as high as 58% at 423 K.
Huang, Xiumin   +6 more
core   +1 more source

Strain in Silica-Supported Ga (III) Sites: Neither Too Much nor Too Little for Propane Dehydrogenation Catalytic Activity

open access: yes, 2020
Well-defined Ga(III) sites on SiO2 are highly active, selective, and stable catalysts in the propane dehydrogenation reaction. In this contribution, we evaluate the catalytic activity towards propane dehydrogenation of tri-coordinated and tetra ...
Christophe, Copéret   +3 more
core   +1 more source

Ethanol Dehydrogenation over Copper-Silica Catalysts: From Atomic Distribution to 15 nm Large Particles

open access: yes, 2022
Non-oxidative ethanol dehydrogenation is a renewable source of acetaldehyde and hydrogen. The reaction is often catalyzed by supported copper catalysts with high selectivity. The activity and long-term stability depend on many factors, including particle
Nicola, Scotti   +6 more
core   +1 more source

Recent Advances in Carbon Cathode Materials toward High‐Performing Zinc‐Ion Hybrid Supercapacitors

open access: yesAdvanced Science, EarlyView.
Aqueous zinc‐ion hybrid supercapacitors (ZHSCs) have emerged as promising next‐generation electrochemical energy‐storage devices. Porous carbon materials have been extensively studied as cathodes, with advances in tailoring pore structures and material properties to enhance performance.
Take Hirooka   +3 more
wiley   +1 more source

π‐Enlargement in Porphyrin Macrocycles at Interfaces

open access: yesAngewandte Chemie, EarlyView.
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán   +11 more
wiley   +2 more sources

A highly efficient Cu/La2O3 catalyst for transfer dehydrogenation of primary aliphatic alcohols

open access: yes, 2010
La2O3-supported copper nanoparticles are sufficiently active for transfer dehydrogenation of primary aliphatic alcohols to aldehydes. When used for 1-octanol, the yield of 1-octanal can be as high as 63%.
Huang, Xiumin   +6 more
core   +1 more source

Silicon Nitride Resistive Memories

open access: yesAdvanced Electronic Materials, EarlyView.
Amorphous SiNx is an attractive resistance switching material for ReRAM applications due to its physicochemical properties, such as humidity resistance, low oxygen diffusivity, and is used as a metal diffusion blocker. By modifying the ratio between N and Si atoms, the microstructure of the SiNx is affected, rendering it possible to change the ...
Alexandros‐Eleftherios Mavropoulis   +7 more
wiley   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

Catalytic Dehydrogenation of Complex Hydrides for Hydrogen Storage

open access: yes, 2011
Hydrogen Storage is one of the pending and challenging technical barriers in the implementation of hydrogen energy.1.2 Amide-hydride and ammonia borane are the two systems attracting considerable attention.
陈萍
core  

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