Results 91 to 100 of about 45,423 (287)

Dehydrogenation of amidoborane ammoniate

open access: yes, 2010
By adding a small amount of HMPA approximately 2.5 equivalent or ca. 8.1 wt% H2 can be released from the LiAlH4–LiNH2 mixture at ambient temperature, which is 370 C lower than the corresponding solid-state dehydrogenation.
何腾   +4 more
core  

Orientation‐Engineered Insulator‐Metal Transition in Vanadium Dioxide

open access: yesAdvanced Science, EarlyView.
Crystallographic orientation engineering in VO2/TiO2 heterostructures enables tunable insulator‐metal transitions. The high‐Miller‐index (102) orientation breaks in‐plane mirror symmetry, inducing anisotropic transport, while its inclined oxygen channels accelerate protonation kinetics.
Xuanchi Zhou   +4 more
wiley   +1 more source

Reactor modeling and kinetic parameters estimation for diethylbenzene (DEB) dehydrogenation reactions [PDF]

open access: yesIranian Journal of Chemical Engineering, 2019
Divinylbenzene (DVB) is produced by catalytic dehydrogenation of DEB at high temperature and atmospheric pressure. Ethylvinylbenzene (EVB) is produced as a useful chemical during dehydrogenation of DEB.
M.E zeynali, H. Abedini, H. R. Sadri
doaj  

Alteration in the Chemical Composition of Immortelle, Silver Fir and Prickly Juniper Essential Oils Induced by Light

open access: yesActa Chimica Slovenica, 2019
The objective of this study was to evaluate impact of light and available oxygen on the chemical composition of three selected essential oils. Aliquots of immortelle (Helichrysum italicum), silver fir (Abies alba) and prickly juniper (Juniperus oxycedrus)
Ilijana Odak   +4 more
doaj   +1 more source

Oxidative Dehydrogenation of Ethane to Ethylene with CO2 over Fe-Cr/ZrO2 Catalysts

open access: yes, 2009
The catalytic performance of Fe-Cr/ZrO2 catalysts, prepared by two different methods-coprecipitation and coprecipitation-impregnation were examined in oxidative dehydrogenation of ethane to ethylene Using CO2 as an oxidant. Thermogravimetric analysis and
Li, Songgeng   +4 more
core   +1 more source

Co‐Ligand‐Induced Electronic Modulation Controls Substrate Adsorption and Selectivity in Biomass Electrooxidation

open access: yesAdvanced Science, EarlyView.
A molecular design strategy is reported that introduces distinct anionic co‐ligands into Cu‐based catalysts to modulate the electronic density of the metal center and, consequently, its interaction with both OHads and HMF. The work establishes co‐ligand engineering as an effective strategy for precise interfacial adsorption control in electrocatalysis,
Chen Gao   +6 more
wiley   +1 more source

Silicon Nitride Resistive Memories

open access: yesAdvanced Electronic Materials, EarlyView.
Amorphous SiNx is an attractive resistance switching material for ReRAM applications due to its physicochemical properties, such as humidity resistance, low oxygen diffusivity, and is used as a metal diffusion blocker. By modifying the ratio between N and Si atoms, the microstructure of the SiNx is affected, rendering it possible to change the ...
Alexandros‐Eleftherios Mavropoulis   +7 more
wiley   +1 more source

Hole‐Activated Lattice Oxygen Enables Pt‐Free Propane Dehydrogenation by Eliminating the Hydrogen Recombination Bottleneck

open access: yesAngewandte Chemie, EarlyView.
Trace Mg doping into gallia–alumina generates hole‐type oxygen species that accelerate hydrogen recombination, eliminating the need for Pt promotion. The fully oxide‐based catalyst resists sintering under repeated regeneration, outperforming benchmark PtSn and CrOx catalysts with exceptional stability over 30 dehydrogenation–regeneration cycles ...
DongHwan Oh   +8 more
wiley   +2 more sources

Safety of Sodium‐Ion Batteries: Evaluation and Perspective from Component Materials to Cells, Modules, and Packs

open access: yesAdvanced Energy Materials, EarlyView.
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim   +5 more
wiley   +1 more source

Vacuum‐Induced Surface Reconstruction of Mn–Ce Oxides for Low‐Temperature Coupled Redox Catalysis

open access: yesAngewandte Chemie, EarlyView.
Near‐surface reconstruction enhances low‐temperature redox catalysis in Mn–Ce mixed oxides. Sequential vacuum annealing and reduced‐pressure O2 treatment enrich Mn near the surface while preserving the CeO2 fluorite framework, promoting interfacial electron redistribution, oxygen activation, and redox cycling.
Yong Yin   +5 more
wiley   +2 more sources

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