Results 181 to 190 of about 45,423 (287)

Modeling Alkylcopper Decomposition Pathway: Deciphering Pre‐Nucleation Processes for Metallic Cu Nanoparticles Synthesis

Chemistry – A European Journal, EarlyView.
Computational study reveals a two‐step decomposition of alkylcopper complexes into (partially) reduced Cu clusters, proposed as prenucleation species for Cu(0) nanoparticle synthesis. Cu‐hydride intermediates and multinuclear centers lower reaction barriers.
Marina Descoubes, Hélène Gérard
wiley   +1 more source

Controlled Amine-Borane Dehydropolymerization Enabled by Mechanistic Insight Using the Ir(^tBu-POCOP)H₂ Catalyst. [PDF]

J Am Chem Soc
Van Beek CM, Sajjad MA, Goodall JC, Lyall CL, Lowe JP, Duckett SB, McIndoe JS, Killeen C, Lloyd-Jones GC, Hintermair U, Macgregor SA, Douthwaite RE, Weller AS.   +12 more
europepmc   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

Chemistry – A European Journal, EarlyView.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua, Alberto Luridiana, Francesco Secci, Emanuele Cocco   +3 more
wiley   +1 more source

Insights into the Mechanism Underlying the Alkane Dehydrogenation Capability of <i>Rhodococcus</i> sp. KSM-B-3M. [PDF]

Microorganisms
Edri N, Buhnik-Rosenblau K, Cohen A, Hakim S, Glaser F, Horev G, Bruffaerts J, Marek I, Kashi Y.   +8 more
europepmc   +1 more source

Unbiased Reaction Network Exploration of C–C Coupling in Methane Dehydroaromatization Over Mo‐ZSM‐5

Chemistry – A European Journal, EarlyView.
Automated reaction route mapping reveals distinct methane coupling pathways over mono‐ and dinuclear Mo carbide species in ZSM‐5. Mononuclear [MoC]2+ selectively forms desorbable C2H4, whereas dinuclear [Mo2C2]2+ promotes strongly adsorbed C3/C4 intermediates linked to coke formation.
Shunsaku Yasumura, Masaru Ogura
wiley   +1 more source

Synergistic Effects of Morphology and Interface Engineering in WO₃/TiO₂ for Photocatalytic Hydrogen Generation. [PDF]

Chem Asian J
Alam S, Rathi C, Dimple, Tsushiro K, Amano F, Verma P.   +5 more
europepmc   +1 more source

Synthesis of Tris(indol‐3‐yl)methanes From Indoles, CO2, and Dimethylphenylsilane With BPh3: Two‐Step Construction of π‐Conjugated Systems

Chemistry – A European Journal, EarlyView.
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li, So Saibara, Reito Yasui, Kazuto Takaishi, Natsumi Nitta, Tadashi Ema   +5 more
wiley   +1 more source

Recent Advances in Solid-State Hydrogen Storage Based on Metal Hydrides and Nanoporous Carbon Materials. [PDF]

Nanomaterials (Basel)
Lesbayev B, Auyelkhankyzy M, Ustayeva G, Rakhymzhan N, Tolynbekov A, Zhamash A, Nazhipkyzy M.   +6 more
europepmc   +1 more source

Well‐Defined Nickel Precatalysts: Form, Function, and Application

Chemistry – A European Journal, EarlyView.
This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John, George A. Koutsantonis, Reto Dorta, Scott G. Stewart   +3 more
wiley   +1 more source

Mechanistic Insights into Light-Driven Acceptorless Dehydrogenation Reactions. [PDF]

Chem Rev
Verhoef CJ, Ma R, Slootweg JC.
europepmc   +1 more source