Results 61 to 70 of about 45,423 (287)

The Effect of the Glycine-to-Oxidant Ratio on the Characteristics and Catalytic Performance of VOx/MgO Catalysts for ODH of n-Octane

open access: yesInorganics
The synthesis of VOx/MgO catalysts by solution combustion synthesis was investigated using varying molar ratios of glycine to oxidant. The effect of varying the fuel amount on morphology, phase composition, surface area, crystallite size, elemental ...
Pinkie Ntola   +7 more
doaj   +1 more source

Defect‐Engineered Microwave‐Responsive Ni@C Composites From Waste PET for Catalytic Plastic Upcycling

open access: yesAdvanced Materials, EarlyView.
A circular upcycling strategy transforms waste poly(ethylene terephthalate) bottles into microwave‐responsive Ni@C catalyst featuring lattice‐distorted nickel cores and defective carbon shells. These strain‐rich heterointerfaces enhance dielectric loss and promote localized microwave hotspots, accelerating peroxymonosulfate activation and polymer‐chain
Xiao Lu   +7 more
wiley   +1 more source

Hydrogen Sorption and Rehydrogenation Properties of NaMgH3

open access: yesMetals, 2022
The formation and hydrogen sorption properties of the NaMgH3 perovskite/type hydride have been examined. Samples were mechanically ball milled under argon for 2, 5 and 15 h; then characterized by X-ray diffraction (XRD), differential scanning calorimetry
Luis Contreras   +4 more
doaj   +1 more source

Magnetization of graphane by dehydrogenation [PDF]

open access: yesApplied Physics Letters, 2009
Using first principles calculations, we show that each hydrogen vacancy created at graphane surface results in a local unpaired spin. For domains of hydrogen vacancies the situation is, however, complex and depends on the size and geometry of domains, as well as whether the domains are single or double sided.
Şahin H., Ataca, C., Ciraci, S.
openaire   +4 more sources

Engineering Metal‐Pocket Cooperativity in Single‐Atom COF Nanozymes for Selective Cascade Catalysis

open access: yesAdvanced Materials, EarlyView.
A multilevel programming strategy is developed to engineer single‐atom COF nanozymes with tunable metal centers and chiral pockets inspired by heme–pocket cooperativity. This approach enables controlled metal–pocket interplay for asymmetric cascade catalysis, delivering high activity, selectivity, and recyclability in an asymmetric oxidation–aldol ...
Ziping Li   +7 more
wiley   +1 more source

Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex [PDF]

open access: yes, 2021
The reversible storage of hydrogen through the intermediate formation of Formic Acid (FA) is a promising solution to its safe transport and distribution.
Alicia, Aloisi   +4 more
core   +2 more sources

A Cu2S/NiOOH Heterojunction Enables Highly Selective Ammonia‐to‐Nitrite Electrooxidation at Industrially Relevant Current Densities

open access: yesAdvanced Materials, EarlyView.
Cu2S/NiOOH heterojunction enables efficient ammonia electrooxidation coupled with hydrogen evolution. Interfacial electronic modulation of Ni sites promotes selective NH3‐to‐NO2− electrooxidation at high current density. In a membrane electrode assembly, Cu2S/NiOOH maintains over 90% Faradaic efficiency of nitrite at 800 mA cm−2, highlighting its ...
Ke Wang   +13 more
wiley   +1 more source

Propane dehydrogenation to propylene over Pt-based catalysts

open access: yes, 2006
Propane catalytic dehydrogenation to propylene was investigated over novel platinum-based catalysts, and the BET, H-2-chemisorption, H-2-TPR, H-2-TPD, C3H6-TPD and O-2-pulse techniques were used for catalyst characterization in this paper.
Li, Wenzhao   +4 more
core   +1 more source

Interface‐Mediated Catalysis for Improved Hydrogen Storage in Reactive Hydride Composites

open access: yesAdvanced Materials, EarlyView.
Catalyst–hydride interfaces are engineered in Co@C‐ and Ni@C‐modified 2LiH + MgB2 reactive hydride composites to accelerate hydrogen uptake and release. Multiscale scattering, in‐situ synchrotron radiation powder x‐ray diffraction and density functional theory calculations reveal the structural and electronic origin of the catalytic enhancement ...
Yuanyuan Shang   +12 more
wiley   +1 more source

Stereoselective synthesis of hernandulcin, peroxylippidulcine A, lippidulcines A, B and C and taste evaluation

open access: yesBeilstein Journal of Organic Chemistry, 2015
The first stereoselective synthesis of lippidulcines A, B and C has been accomplished starting from (+)-hernandulcin, which has been prepared on a multigram scale. The previously assigned absolute configurations have been confirmed. The key steps of this
Marco G. Rigamonti, Francesco G. Gatti
doaj   +1 more source

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