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The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks +8 more
wiley +1 more source
Chemical Recycling of Polycarbonate Acrylonitrile Butadiene Styrene Blends via Organocatalyzed Acetolysis. [PDF]
Pool ME +4 more
europepmc +1 more source
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
wiley +1 more source
Conformation-driven reversibility control in ring-opening metathesis polymerization of non-bicyclic cyclooctenes. [PDF]
Mete TB +7 more
europepmc +1 more source
An entropy‐stabilized Pd/HEO catalyst integrates Lewis acid and hydrogenation sites within a robust oxide–metal interface, enabling efficient and selective conversion of cellulose to ethylene glycol (68.3%) in water. ABSTRACT The selective conversion of cellulose into ethylene glycol (EG) under aqueous conditions is an attractive yet challenging route ...
Dandan Wang +6 more
wiley +1 more source
The cytoskeleton regulates cytoophidium dynamics in Drosophila ovaries. [PDF]
Liu XJ, Li YL, Pang SY, Liu JL, Dou K.
europepmc +1 more source
Fluoro‐functionalized polyether electrolytes, which combine fluorine‐ and ether‐containing groups, achieve enhanced oxidative stability, high ionic conductivity, and superior interfacial stability. Due to their non‐flammability, remarkable flexibility, ease of processing, and design versatility, polymer‐based electrolytes containing polyethers have ...
Nannan Geng +8 more
wiley +1 more source
Adsorptive Decolorization of a Disodium Terephthalate Solution from Monomer Recycling of Polyester. [PDF]
Lücking C, Paschetag M, Scholl S.
europepmc +1 more source
Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen +8 more
wiley +1 more source
A Polycondensation-depolymerization strategy enables closed-loop recyclable polyoxalates <i>via</i> ring-opening polymerization of six-membered cyclic oxalates. [PDF]
Liu Y, Li Z, Zhao D, Shen Y, Li Z.
europepmc +1 more source

