Results 191 to 200 of about 177,844 (287)

Selective Modification of the Product Profile of Biocatalytic Hydrolyzed PET via Product‐Specific Medium Engineering

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks   +8 more
wiley   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

Entropy‐Stabilized Pd/HEO Bifunctional Catalyst for Selective Aqueous‐Phase Hydrogenolysis of Cellulose to Ethylene Glycol

open access: yesEcoEnergy, EarlyView.
An entropy‐stabilized Pd/HEO catalyst integrates Lewis acid and hydrogenation sites within a robust oxide–metal interface, enabling efficient and selective conversion of cellulose to ethylene glycol (68.3%) in water. ABSTRACT The selective conversion of cellulose into ethylene glycol (EG) under aqueous conditions is an attractive yet challenging route ...
Dandan Wang   +6 more
wiley   +1 more source

Fluoro‐Functionalized Polyether Electrolytes Enabling High‐Energy‐Density Solid‐State Lithium‐Metal Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Fluoro‐functionalized polyether electrolytes, which combine fluorine‐ and ether‐containing groups, achieve enhanced oxidative stability, high ionic conductivity, and superior interfacial stability. Due to their non‐flammability, remarkable flexibility, ease of processing, and design versatility, polymer‐based electrolytes containing polyethers have ...
Nannan Geng   +8 more
wiley   +1 more source

Catalytic Hydrogenation of Lignin‐Derived Aromatics With Rhodium Oxide in Water

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The easily available, easy‐to‐handle rhodium(III) oxide, Rh2O3, is shown to be a competent catalyst for arene hydrogenation, including chemoselective reduction of α,β‐unsaturated aryl ketones. Catalytic arene hydrogenation offers a direct pathway to saturated carbocycles. It can also be exploited to upgrade lignin‐derived aromatics.
Zhenyu Chen   +8 more
wiley   +1 more source

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