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Depsidone synthesis. Part 16. Benzophenone–grisa-3′,5′-diene-2′,3-dione–depsidone interconversion: a new theory of depsidone biosynthesis

Journal of the Chemical Society Perkin Transactions 1, 1981
The synthesis of a number of grisa-3′,5′-diene-2′,3-diones by oxidative coupling of substituted 2,2′-dihydroxy-4-methoxybenzophenones is described. The rearrangement of these grisadienediones to depsidones under basic, acidic, and thermal conditions is described and the mechanisms of these reactions are discussed.
Melvyn V Sargent
exaly   +2 more sources

Depsidones from the Endophytic Fungus BCC 8616

Journal of Natural Products, 2006
Three new depsidones (1-3) have been isolated from the endophytic fungus BCC 8616 and their structures analyzed on the basis of spectroscopic data interpretation. Compound 1 exhibited weak cytotoxic activity against breast and epidermoid carcinoma cell lines.
Pattama, Pittayakhajonwut   +5 more
openaire   +2 more sources

Structure of the lichen depsidone gangaleoidin

Journal of the Chemical Society, Perkin Transactions 1, 1975
As a result of degradative, spectroscopic, and synthetic evidence the structure of the lichen depsidone gangaleoidin is revised to methyl 2,4-dichloro-3-hydroxy-8-methoxy-1,6-dimethyl-11-oxo-11H-dibenzo [b,e][1,4]dioxepin-7-carboxylate. Gangaleoidin was degraded to methyl 3-(2-methoxycarbonyl-5-methoxy-3-methylphenoxy)-4,6-dimethoxy-2-methylbenzoate ...
Melvyn V. Sargent   +2 more
openaire   +1 more source

Depsidone synthesis. IV. Caloploicin

Australian Journal of Chemistry, 1976
The synthesis of the lichen depsidone caloploicin (2,4,7-trichloro-3-hydroxy-8-methoxy-1,6,9- trimethyldibenzo[b,e][l,4]dioxepin-11-one) (1) by oxidative coupling of 5'-chloro-2,2',4-trihydroxy-4- methoxy-3',6,6'-trimethylbenzophenone (23), and subsequent steps, is described.
MV Sargent, P Vogel
openaire   +1 more source

ChemInform Abstract: DEPSIDONE SYNTHESIS. PART 16. BENZOPHENONE‐GRISA‐3′,5′‐DIENE‐2′,3‐DIONE‐DEPSIDONE INTERCONVERSION: A NEW THEORY OF DEPSIDONE BIOSYNTHESIS

Chemischer Informationsdienst, 1981
AbstractOxidative Kupplung der substituierten 2,2′‐Dihydroxy‐4‐methoxy‐benzophenone (I), (IV) bzw. (VII) mit K3 [Fe(CN)6] unter optimalen Bedingungen liefert die Grisadiendione (II), (V) bzw. (VIII), die sich bei Thermolyse in fester Form oder in Lösungsmitteln wie TFA/ CHz C12, Diphenylether oder Phenetol in die Depsidone (III), (VI) bzw.
T. SALA, M. V. SARGENT
openaire   +1 more source

Three New Lichen Depsidones

Australian Journal of Chemistry, 1987
The depsidones a- acetylconstictic acid (5-acetoxymethyl-1,4-dihydroxy-10-methoxy-8-methyl-3,7-dioxo-1,3-dihydro-7 H- isobenzofuro [4,5- b][l,4] benzodioxepin-ll-carbaldehyde ) (6), substictic acid (1,4-dihydroxy-10-methoxy-8-methy1-3,7-dioxo- 1,3-dihydro-7 H- isobenzofuro [4,5-b][1,4]benzodioxepin-11-carbaldehyde) (7) and conphysodalic acid (9 ...
JA Elix, KL Gaul, PW James, OW Purvis
openaire   +1 more source

Depsidones from Anomalographis madeirensis

Biochemical Systematics and Ecology, 1999
0 ...
González, Antonio G.   +4 more
openaire   +2 more sources

ChemInform Abstract: DEPSIDONE SYNTHESIS. PART 11. SYNTHESIS OF SOME FUNGAL DEPSIDONES RELATED TO NIDULIN

Chemischer Informationsdienst, 1978
AbstractAusgehend von Oxo‐sulfon (Ia) wird sukzessiv über die angegebenen Stufen das Benzophenon (VIIb) synthetisiert, aus dem durch oxidative Kupplungsreaktion und nachfolgende Debromierung Tridechlordihydro‐nidulin (VIIIb) gewonnen wird.
P. DJURA, M. V. SARGENT
openaire   +1 more source

A new depsidone from Usnea diffracta

Chinese Chemical Letters, 2009
Abstract A new depsidone, diffractione A ( 1 ), as well as six known phenolic compounds ( 2 – 7 ) were isolated from Usnea diffracta . Their structures were elucidated by 1D and 2D NMR spectroscopy together with HRESIMS analysis. All components were obtained for the first time from U. diffracta.
Huan Yang Qi   +2 more
exaly   +2 more sources

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