Results 91 to 100 of about 50,053 (275)

Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+ [PDF]

, 2017
We report the preparation and characterization of a new family of four polyoxothiometalate (POTM) clusters, with varying size and complexity, based upon the dimeric [Mo2O2S2(H2O)6]2+ with the general formula (NMe4)aKb[(Mo2O2S2)c(TeO4)d(C4O4)e(OH)f] where
Cronin, Lee, Long, De-Liang, Markopoulou, Panagiota, Miras, Haralampos, Purcell, Jamie W.   +4 more
core   +1 more source

Redefining Separator Design and Water Activity for High‐Energy Zinc Batteries Using Covalent Organic Framework

Advanced Materials, EarlyView.
Device‐level zinc batteries are energy‐limited by the mass/volume of inactive components, while lean‐electrolyte operation triggers interfacial water depletion and unstable kinetics. Here we elucidate lean‐failure mechanisms and develop a COF@PAN functional separator that regulates hydrogen‐bonding networks to manage water activity and accelerate ...
Kun Zhang, Hongtian Liu, Yiwei Zhao, Yijia Yuan, Shibo Xi, Yaohua Zhao, Li Ma, Changan Lu, Shuanglin Wu, Xiaomei Huo, Jia Liu, Keyu Xie, Kian Ping Loh   +12 more
wiley   +1 more source

Homogeneous Organic Crystal Nucleation Rates in Solution from the Perspective of Chemical Reaction Kinetics

Crystals
It is demonstrated for 11 different combinations of organic solutes and solvents that the supersaturation dependence of homogeneous organic crystal nucleation rates from solution can be predicted from the solubility, bar a single empirical rate constant,
Sven L. M. Schroeder
doaj   +1 more source

Crystal structure, thermal crystal form transformation, desolvation process and desolvation kinetics of two novel solvates of ciclesonide

RSC Advances, 2016
Two novel solvates of ciclesonide were successfully obtained and characterized by various analytical techniques (XRPD, XRSD, DSC, TGA and HSM). Thermal crystal form transformation and desolvation process of the solvates were also studied.
Lina Zhou, Qiuxiang Yin, Shichao Du, Hongxun Hao, Yanfeng Li, Mingyan Liu, Baohong Hou   +6 more
openaire   +1 more source

Evidence of the indirect hormonal activity of prohormones using liver S9 metabolic bioactivation and an androgen bioassay [PDF]

, 2008
Prohormones such as dehydroepiandrosterone (DHEA) are steroid precursors that do not show hormonal activity by themselves. Abuse of these prohormones in cattle fattening is hard to prove because of strong in vivo metabolism and the difficulty to detect ...
Bovee, T.F.H., Groot, M.J., Nielen, M.W.F., Peijnenburg, A.A.C.M., Rijk, J.C.W.   +4 more
core   +2 more sources

Self‐Regulating Sodium‐Ion Battery Materials: From Phase Reconstruction to Functional Activation

Advanced Materials, EarlyView.
Self‐regulating sodium‐ion batteries hinge on programmable phase behavior in layered oxides, interphases that renew without growth, and electrolytes that steer solvation and chemistry. This review distills mechanisms into design rules that span composition, site and entropy tuning, and self‐buffering anodes, linking operando evidence to choices and ...
Hong Gao, Dingyi Zhang, Chao Wang, Tianxiao Chen, Xingwang Peng, Yuxiu Xing, Xin Guo, Yufei Zhao, Yong Wang, Guoxiu Wang, Hao Liu   +10 more
wiley   +1 more source

Regulating a NaF‐Rich SEI Layer for Dendrite‐Free Sodium Metal Batteries Using Trifunctional Halogenated Covalent Organic Framework Separators

Advanced Science
Uncontrolled sodium‐ion (Na+) transport, fragile solid electrolyte interphase (SEI) layers, in and sluggish Na+ desolvation using conventional separators drive dendrite growth, posing critical challenges to the development of sodium metal batteries (SMBs)
Muhammad Ali, Hamid Hussain, Moazzam Ali, Samia Aman, Weiwei Yang, Zeeshan Ali, Lei Li, Yinzhu Jiang, Muhammad Yousaf   +8 more
doaj   +1 more source

local fraction desolvated

, 2014
Citation: 'local fraction desolvated' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.L03605 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Ultra-low temperature structure determination of a Mn12 single-molecule magnet and the interplay between lattice solvent and structural disorder [PDF]

, 2013
We have determined the ultra-low temperature crystal structure of the archetypal single-molecule magnet (SMM) [Mn12O12(O2CMe)16(H2O)4]·4H2O·2MeCO2H (1) at 2 K, by using a combination of single-crystal X-ray and single-crystal neutron diffraction. This is
Andrew R. Farrell, Andrès E. Goeta, Bardeau, Betteridge, Bogani, Campbell, Caneschi, Chakov, Cornia, Cornia, De Raedt, del Carmen Giménez-López, Domingo, Evangelisti, Evangelisti, Friedman, Hill, Hill, Jonathan A. Coome, Judith A. K. Howard, Kirchner, Langan, Larionova, Lis, Marie-Hélène Lemée-Cailleau, Mark Murrie, McIntyre, Michael R. Probert, Milios, Mirebeau, Murrie, Palatinus, Parois, Probert, Redler, Rinehart, Rinehart, Sessoli, Sessoli, Sheldrick, Simon Parsons, Takahashi, Thomas, Troiani, Waldmann, Wernsdorfer, Wilkinson, Wilkinson, Wu, Zakharov   +49 more
core   +2 more sources

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

Advanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar, Timo Weintraut, Sebastian L. Benz, Semih Engün, Sascha Kremer, Anja Henss, Felix H. Richter   +6 more
wiley   +1 more source