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The combination of electrochemistry (EC) and mass spectrometry (MS) is a powerful analytical tool for studying mechanisms of redox reactions, identification of products and intermediates, and online derivatization/recognition of analytes.
Pengyuan Liu +2 more
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Synchronized Inductive Desorption Electrospray Ionization Mass Spectrometry
Angewandte Chemie - International Edition, 2011Guangming Huang +2 more
exaly +3 more sources
Analytical Chemistry, 2005
Desorption electrospray ionization (DESI), an ambient mass spectrometry technique, is used for trace detection of the explosives trinitrohexahydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), 2,4,6-trinitrotoluene (TNT), Pentaerythritol tetranitrate (PETN), and their plastic compositions (Composition C-4, Semtex-H ...
Ismael, Cotte-Rodríguez +4 more
openaire +2 more sources
Desorption electrospray ionization (DESI), an ambient mass spectrometry technique, is used for trace detection of the explosives trinitrohexahydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), 2,4,6-trinitrotoluene (TNT), Pentaerythritol tetranitrate (PETN), and their plastic compositions (Composition C-4, Semtex-H ...
Ismael, Cotte-Rodríguez +4 more
openaire +2 more sources
Rapid Communications in Mass Spectrometry, 2017
Rationale Although it is claimed that desorption electrospray ionization (DESI) causes less ion suppression effects than electrospray ionization (ESI), a related investigation with quantification measurement of ion suppression effects is absent.
Zheng Wang, Haijing Zhu, Guangming Huang
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Rationale Although it is claimed that desorption electrospray ionization (DESI) causes less ion suppression effects than electrospray ionization (ESI), a related investigation with quantification measurement of ion suppression effects is absent.
Zheng Wang, Haijing Zhu, Guangming Huang
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Desorption Electrospray Ionization in a Small Pressure-Tight Enclosure
Analytical Chemistry, 2007Desorption electrospray ionization (DESI) is made easier to implement, more robust, and exposure of the analyst to the sample is reduced by a novel DESI interface. This features a small, pressure-tight enclosure with fixed spatial relationships between the sprayer, surface, and sampling capillary.
Andre, Venter, R Graham, Cooks
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Synchronized Desorption Electrospray Ionization Mass Spectrometry Imaging
Analytical Chemistry, 2015Desorption electrospray ionization (DESI) has emerged as a powerful technique for mass spectral analysis and imaging under ambient conditions. Synchronization of DESI (sDESI) with the ion injection period (IT)of low-duty cycle mass spectrometers has been previously shown to improve sensitivity and reduce the amount of sample depleted during the ...
Comi, Troy J. +2 more
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Analytical and Bioanalytical Chemistry, 2023
The imaging of biological tissues can offer valuable information about the sample composition, which improves the understanding of analyte distribution in such complex samples. Different approaches using mass spectrometry imaging (MSI), also known as imaging mass spectrometry (IMS), enabled the visualization of the distribution of numerous metabolites,
Lanaia Ítala Louzeiro Maciel +6 more
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The imaging of biological tissues can offer valuable information about the sample composition, which improves the understanding of analyte distribution in such complex samples. Different approaches using mass spectrometry imaging (MSI), also known as imaging mass spectrometry (IMS), enabled the visualization of the distribution of numerous metabolites,
Lanaia Ítala Louzeiro Maciel +6 more
openaire +2 more sources
Desorption Electrospray Ionization: Achieving Rapid Sampling Rates
Analytical Chemistry, 2009The sampling rate and imaging capabilities of desorption electrospray ionization (DESI) are examined using a rotating sample platform combined with Hadamard transform time-of-flight mass spectrometry (HTTOFMS), a multiplexed time-of-flight technique that allows for millisecond acquisition of full mass-to-charge ratio scans.
Griffin K, Barbula +4 more
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Probe-Substrate Distance Control in Desorption Electrospray Ionization
Journal of the American Society for Mass Spectrometry, 2017We introduce probe-substrate distance (Dps)-control to desorption electrospray ionization (DESI) and report a systematic investigation of key experimental parameters. Examination of voltage, flow rate, and nebulizing gas pressure suggests as Dps decreases, the distance-dependent spray current increases, until a critical point. At the critical point the
Tyler J, Yarger +2 more
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Desorption electrospray ionization mass spectrometry of intact bacteria
Journal of Mass Spectrometry, 2007AbstractDesorption electrospray ionization (DESI) mass spectrometry (MS) was used to differentiate seven bacteria species on the basis of their measured DESI‐mass spectral profile. Both gram‐positive and gram‐negative bacteria were tested and included Escherichia coli, Staphyloccocus aureus, Enterococcus sp., Bordetella bronchiseptica, Bacillus ...
Mohammed A, Meetani +4 more
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