Characterization of human plasma proteome dynamics using deuterium oxide. [PDF]
Wang D +8 more
europepmc +1 more source
Description of the rate‐limiting hydrogen tunneling mechanism for plant 9‐ and 13‐lipoxygenases
Abstract Soybean lipoxygenase (GmLOX1), a plant 13‐LOX, has long been considered a model protein for non‐trivial, quantum hydrogen tunneling in enzyme catalysis. Hydrogen tunneling mechanisms have also been confirmed for LOXs across mammalian, fungal, and bacterial kingdoms.
Alex Kockler +7 more
wiley +1 more source
Hydrogen Removal from Fe at Room Temperature: A Study on Hydrogen Trapping Mechanisms. [PDF]
Zhang K, Li H, Guan D.
europepmc +1 more source
1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications
In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to C‐C, C‐heteroatom, and multicomponent products. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and
Jayaram Vankudoth +2 more
wiley +1 more source
Integrating Simple Microfluidics Design/Fabrication with a Novel Ionization Source for Time-Resolved Chemical Reaction Studies by Mass Spectrometry. [PDF]
Overby A +6 more
europepmc +1 more source
Electroreductive Desulfurization of Thioacetals
A metal‐free electrochemical protocol enabled desulfurization of thioacetals under ambient conditions. Aryl substituents on sulfur act as internal electroauxiliaries to promote C(sp3)─S bond cleavage via a radical pathway, effectively serving as alternative to the Mozingo reduction.
Ellymay Goossens +7 more
wiley +1 more source
Molecular dynamics simulations of the sputtering of boron and boron oxide surfaces. [PDF]
Shermukhamedov S +3 more
europepmc +1 more source
Racemisation of Amino Acids: From Synthetic Challenge to Biological Significance
Racemisation, once considered an undesirable synthetic side reaction, also occurs naturally in amino acids and influences biological processes. Evidence links stereochemical conversion to ageing, protein turnover, and cellular development. This review examines mechanisms, control strategies in synthesis, applications and implications in physiology ...
Othman Al Musaimi
wiley +1 more source
Carbon‐Supported NiZnO Nanoparticles for Electrochemical Reduction of CO2 to Hydrocarbons
Electronic interaction between nickel and zinc (oxide) in highly dispersed NiO‐ZnO nanoparticles on carbon support leads to improved Faradaic efficiency to C1−3 hydrocarbons in CO2 electroreduction at low ZnO concentrations (20:1 Ni: Zn ratio). Higher ZnO content (10:1 Ni:Zn ratio) favors the competing hydrogen evolution reaction, while only CO was ...
Matt L. J. Peerlings +8 more
wiley +1 more source
Hydrogen Activation via Dihydride Formation on a Rh<sub>1</sub>/Fe<sub>3</sub>O<sub>4</sub>(001) Single-Atom Catalyst. [PDF]
Wang C +12 more
europepmc +1 more source

