Structural and Functional Siderophore Remodeling by Enzymatic Delipidation
A surprising functional switch in bacterial siderophores was discovered through genome mining and the analysis of environmental and pathogenic Pandoraea species. Pandorachelin B, a lipocyclopeptide that promotes swarming motility, is cleaved by a specialized acylase, yielding a ring‐contracted, homodetic cyclopeptide, pandorachelin A, which exhibits ...
Elena Herzog +5 more
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D<sub>2</sub>O-Enabled Chemical Beaconing: Tracking Steroid Metabolism by Pooled Gut Microbiota. [PDF]
Tupertsev B +3 more
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Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley +2 more sources
New perspectives on the physiological basis of muscle loss
Experimental Physiology, EarlyView.
Alistair J. Monteyne, Marlou L. Dirks
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A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu +11 more
wiley +2 more sources
Probing protein-lipid interactions by hydrogen/deuterium exchange-mass spectrometry: advances, challenges and future directions. [PDF]
Lioupi A, Gavriilidou AFM, Politis A.
europepmc +1 more source
<sup>2</sup>H<sub>2</sub>O labeling methods for bulk and single muscle protein synthesis measures, and measures of integrated muscle protein synthesis and breakdown rates: A pilot study. [PDF]
Højfeldt G +7 more
europepmc +1 more source
<i>In Vivo</i> Real-Time Metabolic Isotopic Tracing via Breath Analysis upon Deuterated Water Ingestion: A Proof-of-Concept Study. [PDF]
Yin Z +7 more
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Equilibrium-driven decarbonylative multi-deuteration enables access to highly deuterated carbon frameworks. [PDF]
Lee J, Park T, Park JE, Moon HW, Lee S.
europepmc +1 more source
Unanticipated enhancement of phosphide nucleophilicity in dimethyl sulfoxide for advanced catalytic P-C bond formation reactions. [PDF]
Finfer EJ +4 more
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