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Unveiling anharmonic coupling by means of excited state ab initio dynamics: application to diarylethene photoreactivity.

Physical Chemistry, Chemical Physics - PCCP, 2019
In this work, excited state ab initio molecular dynamics together with a time resolved vibrational analysis is employed to shed light on the vibrational photoinduced dynamics of a well-known diarylethene molecule experiencing a ring opening reaction upon
M. Chiariello   +3 more
semanticscholar   +1 more source

Photochromic diarylethenes for molecular photonics

Supramolecular Science, 1996
Abstract 1,2-Diarylethenes with heterocyclic aryl groups, such as benzothiophene rings, underwent thermally irreversible and fatigue resistant photochromic reactions. The photocyclization response time of a dithienylethane was measured to be 1 ps.
openaire   +1 more source

Diarylethenes with Heterocyclic Aryl Groups

2006
Although in the presence of air the dihydrophenanthrene irreversibly converts to phenanthrene by hydrogen elimination with oxygen, it thermally returns to the initial stilbene in the absence of oxygen. When methyl groups are substituted at 2and 6positions of the phenyl rings, the compound undergoes a reversible photocyclization reaction, even in the ...
openaire   +1 more source

Ultrakurzzeitspektroskopie zum Schaltverhalten substituierter Diarylethene

2008
Die Informationstechnologie revolutioniert das tägliche Leben seit Jahrzehnten. Der stetig steigende Umfang zu speichernder und zu bearbeitender Daten motiviert die Suche nach Schalt- und Speicherbausteinen in der Größenordnung einzelner Moleküle.
openaire   +1 more source

Significant Enhancement of C2 H2 /C2 H4 Separation by a Photochromic Diarylethene Unit: A Temperature- and Light-Responsive Separation Switch.

Angewandte Chemie, 2017
C. Fan   +11 more
semanticscholar   +1 more source

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