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New Thermally Irreversible and Fluorescent Photochromic Diarylethenes

The Journal of Physical Chemistry A, 2008
A photokinetic investigation is here carried out on four newly synthesized diarylethenes with the aim to test their performance as photoreversible chromogenic and light emitting materials. The pentatomic ring, which fixes these diarylethenes in the cis conformation, contains a Si atom or a PO group.
Cipolloni M.   +5 more
openaire   +3 more sources

Radiation Sensitivity of Photochromic Diarylethenes

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 2000
Abstract The radiation sensitivity of photochromic dithienylethenes was studied with the aim of developing a new reusable color film dosimeter. Upon γ-irradiation, polystyrene films containing 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene 1 and 1,2-bis(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene 2 turned red and blue, respectively. The red
S. Irie, M. Irie
openaire   +1 more source

A dual-functional fluorescent sensor based on diarylethene for Zn2+ and Al3+ in different solvents

Journal of Photochemistry and Photobiology A: Chemistry, 2019
A novel diarylethene derivative containing a purine unit has been successfully synthesized. It not only exhibited multiple controllable fluorescent switching properties with the stimuli of metal ions, and UV/vis lights, but also showed high selectivity ...
Zhen Wang, S. Cui, Shouyu Qiu, S. Pu
semanticscholar   +1 more source

Turn-On Mode Fluorescent Diarylethenes

2017
Turn-on mode highly fluorescent photochromic chromophores, which are initially non-luminous under irradiation with visible light but activated to emit fluorescence upon irradiation with UV light, have been developed. The chromophores are sulfone derivatives of 1,2-bis(2-alkyl-1-benzothiophen-3-yl)perfluorocyclopentene.
Masakazu Morimoto, Masahiro Irie
openaire   +1 more source

Electrochromism of photochromic diarylethene derivative

SPIE Proceedings, 2005
The diarylethene may undergo photochemical ring-closing reaction and both photochemical and electrochemical ring-opening reaction. Irradiation of the open form with UV light results in essentially quantitative photocyclization to the deeply colored form.
Xinhong Zhou   +6 more
openaire   +1 more source

Discovery and development of photochromic diarylethenes

Pure and Applied Chemistry, 2015
Abstract A new family of thermally irreversible photochromic molecules, named “diarylethene,” was serendipitously discovered a quarter of a century ago. The diarylethenes undergo thermally irreversible, fatigue resistant, ultrafast and highly sensitive photochromic reactions.
openaire   +1 more source

Diarylethenes that Photoswitch with Visible Light

2017
Two approaches to prepare visible-light-sensitive diarylethene (DAE) derivatives are described. One is direct excitation of well-designed DAE derivatives with visible light and the other is indirect visible-light excitation to a reactive triplet state by a triplet energy transfer.
Tuyoshi Fukaminato, Masahiro Irie
openaire   +1 more source

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