Results 51 to 60 of about 6,752 (176)

Transfer Hydrogenation of Organic Azides to Amines by Ammonia Borane Complex Under Mild Conditions Catalyzed by Reusable Au Nanoparticles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda   +5 more
wiley   +1 more source

Diarylmethyl Ethers for the Protection of Polyols

open access: yesJournal of Chemistry, 2013
The paper discusses the use of diarylmethyl ethers for the protection of hydroxyl groups, in particular, carbohydrate hydroxyl groups. The formation of these ethers can be done nonselectively by the thermal reactions of diryldiazomethanes via a carbene ...
Sigthor Petursson
doaj   +1 more source

Comprehensive Evaluation of Bisphenol A Toxicity Reveals Neurobehavioral, Metabolic, and Reproductive Impairments in Girardia tigrina

open access: yesEnvironmental Toxicology, EarlyView.
ABSTRACT Bisphenol A (BPA), a common industrial chemical used in plastics and consumer products, is increasingly detected in aquatic environments, raising serious concerns about its potential ecological impacts. This study evaluated the sublethal and acute toxic effects of BPA on the freshwater planarian Girardia tigrina, a recognized model for ...
Raquel de Jesus Selestrino   +2 more
wiley   +1 more source

Recent advances in asymmetric [2+1] cycloaddition with α-cyano diazo compounds

open access: yesTetrahedron Chem
The asymmetric [2 + 1] cycloaddition of α-cyano diazo compounds has emerged as an efficient and versatile strategy for synthesizing cyano-substituted cyclopropanes, which are valuable scaffolds in medicinal chemistry, materials science, and natural ...
Shuicai Chen   +5 more
doaj   +1 more source

Modulation of KATP channels by diazoxide preserves mitochondrial function and barrier integrity under staurosporine‐induced epithelial stress

open access: yesBritish Journal of Pharmacology, EarlyView.
Background and Purpose Intestinal barrier dysfunction caused by mitochondrial stress, oxidative damage and apoptosis, are hallmarks of dysbiosis‐associated gastrointestinal (GI) disorders. Staurosporine causes downstream features of dysbiosis‐induced epithelial damage.
Fatima Maqoud   +9 more
wiley   +1 more source

Mechanistic Study of the Light‐Initiated Generation of Free Diazoalkanes: Towards Photo‐Orthogonal Synthesis

open access: yesChemistryEurope
An in‐depth mechanistic study for the photogeneration of free diazoalkanes from N‐tosylhydrazone precursors by combining observations from synthesis with spectroscopic and theoretical methods is presented.
Ferdinand L. Pointner   +12 more
doaj   +1 more source

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

open access: yesChemistry – A European Journal, Volume 32, Issue 10, 9 March 2026.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim   +4 more
wiley   +1 more source

Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

open access: yesAdvanced Materials, Volume 38, Issue 16, 17 March 2026.
Crystal engineering enables systematic study of structure/function relationships as exemplified by pore engineering of reticular sorbents, including porous coordination networks and covalent organic frameworks. This review assesses such studies applied across the full scope of industrially relevant hydrocarbon separations to provide insight into how ...
Xia Li   +2 more
wiley   +1 more source

Biodegradable Adhesive Systems for Bio‐Integrated Applications

open access: yesAdvanced Science, Volume 13, Issue 15, 13 March 2026.
Biodegradable adhesives provide temporary yet reliable adhesion while degrading into safe, non‐toxic by‐products under physiological or environmental conditions. This review summarizes recent developments in physical and chemical adhesion mechanisms—including hydrogen bonding, catechol chemistry, amine‐carboxyl coupling, and emerging diazirine and urea
Won Bae Han   +6 more
wiley   +1 more source

Monoaminylation in Human Health and Disease: State of the Field, Challenges, and Emerging Directions

open access: yesAdvanced Science, Volume 13, Issue 16, 18 March 2026.
This review delineates monoaminylation—serotonylation, dopaminylation, and histaminylation—as key post‐translational modifications beyond receptor signaling. It details their catalytic mechanisms, roles in gene expression and protein function, and implications in health and disease, aiming to bridge mechanistic insights with therapeutic potential ...
Yiqi Zhao   +4 more
wiley   +1 more source

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