Results 81 to 90 of about 6,933 (191)
Triphenyl{(E)-4-[4-(phenyldiazenyl)phenyl]-4H-1,2,4-triazol-1-yl}boron
Acta Crystallographica Section E, 2009 In the title compound, C32H26BN5 or [(C14H11N5)B(C6H5)3], the B atom is approximately tetrahedrally coordinated. The diazo unit is in a trans conformation, which is generally more stable than a cis one for aromatic azo compounds.
Daisuke Urakami +2 more
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Counterion Effects on the Properties and Reactivity of Charged Photoredox Catalysts
ChemPhotoChem, Volume 10, Issue 8, August 2026.The choice of a counterion for a charged photocatalyst has long been overlooked. In this review, we summarize recent reports on counterion effects in photocatalysis, providing readers with a comprehensive theoretical understanding and synthetic applications for the use of a carefully chosen counterion. Electrostatic interactions represent the strongest
Elina K. Taskinen, Burkhard König
wiley +1 more source
Main Group Metals in Redox Catalysis
European Journal of Inorganic Chemistry, Volume 29, Issue 22, 1 August 2026.Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki +2 more
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Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
Angewandte Chemie, Volume 138, Issue 29, 13 July 2026.Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera +2 more
wiley +2 more sources
Isoxazolium N-ylides and 1-oxa-5-azahexa-1,3,5-trienes on the way from isoxazoles to 2H-1,3-oxazines
Beilstein Journal of Organic Chemistry, 2014 Theoretical and experimental studies of the reaction of isoxazoles with diazo compounds show that the formation of 2H-1,3-oxazines proceeds via the formation of (3Z)-1-oxa-5-azahexa-1,3,5-trienes which undergo a 6π-cyclization.
Alexander F. Khlebnikov +6 more
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Laryngoscope Investigative Otolaryngology, Volume 11, Issue 4, August 2026.ABSTRACT Background Benign tracheal stenosis, characterized by granulation hyperplasia, is a rare and serious disease threatening human health. Interventional bronchoscopy demonstrates limited therapeutic efficacy and poses a risk of re‐injury to the airway.
Dengyuan Li +4 more
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Angewandte Chemie, Volume 138, Issue 29, 13 July 2026.A nanopore composed of transmembrane peptides and a DNA scaffold that assists peptide assembly was constructed. By employing peptides containing the unnatural amino acid 2‐aminoisobutyric acid (Aib), which promotes loose packing between helices, a large‐diameter nanopore was achieved.
Zugui Peng +3 more
wiley +2 more sources
ReactionsThis work reports the synthesis of aminoazobenzene compounds derived from 3,5-dimethylaniline (1a–1f) via a diazo-coupling reaction with aromatic amines.
David Fernando Venegas-Villalvazo +5 more
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Journal of Physical Organic Chemistry, Volume 39, Issue 8, August 2026.The photochemistry of ethyl 2‐diazo‐3,3,3‐trifluoropropanoate shows that its excited singlet state undergoes internal conversion, carbene formation, and diazirine formation. The resulting singlet carbene reacts through solvent‐dependent pathways, forming ylides in methanol and acetonitrile or a C–Cl insertion product in chloroform.
Jojo Joseph +8 more
wiley +1 more source
Lightening Diazo Compounds? [PDF]
ACS Sustainable Chemistry & Engineering, 2021 Jakub Durka +2 more
openaire +1 more source