Overcrowded Alkene Photo‐Redox‐Switches Based on Quinolinium/Carbene Building Blocks
A modular synthesis of a new class of photo‐ and redox‐switches is described based on the combination of quinolinium salts and carbenes. Photochemical switching allows to selectively switch between folded E/Z isomers, while electrochemical switching allows to change between neutral, radical cation and dicationic oxidation states, which are all isolable
Chris Burdenski +10 more
wiley +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source
Cobalt Diazo-Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate. [PDF]
Aghazada S +4 more
europepmc +1 more source
Visible Light Induced Brønsted Acid Assisted Pd-Catalyzed Alkyl Heck Reaction of Diazo Compounds and N-Tosylhydrazones. [PDF]
Zhang Z +3 more
europepmc +1 more source
Atom insertion represents a powerful yet conceptually challenging mode of skeletal editing, as it requires controlled cleavage and reorganization of strong covalent bonds within an existing molecular framework.
Yuki Konno, Mahito Atobe, Naoki Shida
doaj +1 more source
Stereoselective Synthesis of Tri- and Tetrasubstituted Olefins via 1,6-Additions of Diazo Compounds and Their Precursors to p-Quinone Methides. [PDF]
Pati S, Rayi S, Namboothiri INN.
europepmc +1 more source
Overcoming O-H Insertion to Para-Selective C-H Functionalization of Free Phenols: Rh(II)/Xantphos Catalyzed Geminal Difunctionalization of Diazo Compounds. [PDF]
Yang Y, Lu B, Xu G, Wang X.
europepmc +1 more source
Yoshiro OGATA, Masaru TSUCHIDA
openaire +3 more sources
Understanding the Influence of Donor-Acceptor Diazo Compounds on the Catalyst Efficiency of B(C6 F5 )3 Towards Carbene Formation. [PDF]
Babaahmadi R +5 more
europepmc +1 more source
Fe-Catalyzed Selective Formal Insertion of Diazo Compounds into C(sp)-C(sp3) Bonds of Propargyl Alcohols: Access to Alkyne-Substituted All-Carbon Quaternary Centers. [PDF]
Wang DK +7 more
europepmc +1 more source

