Results 101 to 110 of about 9,657 (231)

Genome Mining for Diazo-Synthesis-Related Genes in Streptomyces sp. CS057 Unveiled the Cryptic Biosynthetic Gene Cluster crx for the Novel 3,4-AHBA-Derived Compound Crexazone 2

open access: yesBiomolecules
Natural products play a crucial role in drug development, addressing the escalating microbial resistance to antibiotics and the treatment of emerging diseases. Progress in genome sequencing techniques, coupled with the development of bioinformatics tools
Laura Prado-Alonso   +9 more
doaj   +1 more source

Original Reactivity of ?-Diazo-?- ketoesters Catalyzed by CpRu Complexes

open access: yesCHIMIA, 2014
Using ?-diazo-?-ketoesters as reagents and combinations of CpRu fragments and diimine ligands as catalysts, a series of original transformations have been obtained that can be rationalized by the formation of metal carbenes and metal-bound ylide
Cecilia Tortoreto   +4 more
doaj   +1 more source

Enzyme–MOF Composites: Quantitative Benchmarking and Evaluation of Biocatalyst Performance

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 13, 2 July 2026.
Rigorous evaluation of enzyme@MOF composites requires quantitative benchmarking. This study illustrates this approach by applying and comparing enzyme‐loading and activity‐assessment strategies for two structurally and functionally distinct enzymes, phenolic acid decarboxylase, and cytochrome c.
Annika J. Weber   +9 more
wiley   +1 more source

Hydrogen Atom Transfer: An Intramolecular Main‐Group Metal‐Ligand Cooperative Biradical Pathway

open access: yesChinese Journal of Chemistry, Volume 44, Issue 13, Page 2121-2127, 1 July 2026.
The molecular system consisting of a main‐group metal and a redox‐active ligand, ((2,6‐iPr2C6H3)NC(Me))2AlCl(THF), has been shown to react with azides and diazomethanes, yielding products through both a biradical intermediate and a hydrogen atom transfer process.
Ting Chen   +6 more
wiley   +1 more source

Synthesis of a-Diazo Carbonyl Compounds with the Shelf-Stable Diazo Transfer Reagent Nonafluorobutanesulfonyl Azide

open access: yes, 2011
5 páginasNonafluorobutanesulfonyl azide is a shelf-stable, cost-effective and general diazo transfer reagent for the efficient synthesis of a-diazo carbonyl compounds in excellent yields and in very short reaction times, under mild conditions.
José Ramón Suárez   +3 more
core   +1 more source

Isoxazolium N-ylides and 1-oxa-5-azahexa-1,3,5-trienes on the way from isoxazoles to 2H-1,3-oxazines

open access: yesBeilstein Journal of Organic Chemistry, 2014
Theoretical and experimental studies of the reaction of isoxazoles with diazo compounds show that the formation of 2H-1,3-oxazines proceeds via the formation of (3Z)-1-oxa-5-azahexa-1,3,5-trienes which undergo a 6π-cyclization.
Alexander F. Khlebnikov   +6 more
doaj   +1 more source

Compostos alfa-diazo carbonílicos: uma estratégia atraente para a síntese orgânica alpha-diazo carbonyl compounds: an atractive estrategy in organic synthesis

open access: yesQuímica Nova, 2001
Diazocarbonyl compounds are a very important class of organic substances which have a long history of useful aplications in organic chemistry. The focus of this report deals with the use of diazocarbonyl compounds in a ariety of important reactions and ...
Vítor F. Ferreira   +3 more
doaj   +1 more source

Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Cl3CCN/NaH and Rh(II)-Catalyzed Reaction of β-Trichloroacetylamino α-Diazo Carbonyl Compounds

open access: yes, 2016
The hydroxyl group was directly converted into the trichloroacetylamino group by reacting β-hydroxy α-diazo carbonyl compounds with Cl3CCN and NaH.
Shiwei Zhang (2394778)   +5 more
core   +2 more sources

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer   +6 more
wiley   +1 more source

Pyridine Group Assisted Addition of Diazo-Compounds to Imines in the 3‑CC Reaction of 2‑Aminopyridines, Aldehydes, and Diazo-Compounds

open access: yes, 2016
A novel three-component coupling (3-CC) reaction of 2-aminoazines, aromatic aldehydes, and diazo-compounds producing polyfunctional β-amino-α-diazo-compounds has been developed.
Victoria Helan (1991983)   +3 more
core   +1 more source

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