Nitrolysis of a Highly Deactivated Amide by Protonitronium. Synthesis and Structure of HNFX1
Efficient N-nitrolysis of highly deactivated 3,3,7,7-tetrakis(difluoramino)octahydro-1,5-bis(4-nitrobenzenesulfonyl)-1,5-diazocine (1) has been achieved by the use of protonitronium reagent formed in the system nitric acid−trifluoromethanesulfonic acid ...
Charles B. Kreutzberger (3042687) +3 more
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Synthesis and Characterization of New Diazocine Derivatives for Application in Photopharmacology and Material Science [PDF]
The incorporation of photoswitchable molecules into biological or technical systems is a promising approach for the selective control of such processes at the molecular level.
Brandt, Thomas
core +1 more source
An efficient protocol has been developed for the exo-mono and exo,exo-bis functionalization of Tröger's base in the benzylic 6 and 12 positions of the diazocine ring.
Dawaigher, Sami +15 more
core +1 more source
Synthesis of dibenzo-[bf][1,5]diazocine-based hosts and their assembly behaviors with C-60 [PDF]
Diaryl[bf][1,5]diazocine-based macrocycles 5 and 6 with inner cavities have been synthesized via Hay coupling method. Single crystal of 5 shows that it forms a dimeric aggregate via the weak intermolecular interactions between two adjacent rings, which
Jiang, Yi +3 more
core
π-Conjugated azobenzene derivatives were reported to couple azo moieties with aryl fluorophore. Using the photochemistry of the C2-bridged azobenzene, we have accomplished two diazocine-based photoswitching molecules (cAz1 and cAz2).
Qian Zhu (191342) +5 more
core +1 more source
Stille vs. Suzuki - cross-coupling for the functionalization of diazocines. [PDF]
Walther M +3 more
europepmc +1 more source
[1,4]Diazocine-Embedded Electron-Rich Nanographenes with Cooperatively Dynamic Skeletons
Curved nanographenes (NGs) are emerging as promising candidates for organic optoelectronics, supramolecular materials, and biological applications. Here we report a distinctive type of curved NGs bearing a [1,4]diazocine core that is fused with four ...
Chengshuo Shen (1749448) +3 more
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The Bio-herbicidal potential of some wild plants with allelopathic effects from Tabuk Region on selected local weed species. [PDF]
Alanaz AR +7 more
europepmc +1 more source
Substrate Switchable Pathway for Selective Construction of Bridged Dibenzo[b,f][1,5]diazocines and Bridged Spiromethanodibenzo[b,e]azepines. [PDF]
Pramanik S +3 more
europepmc +1 more source
Conditions for the introduction of terminal alkynes into the 2- and 8-positions of the Troger's base core via Sonogashira reaction of 2,8-diiodo-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine were established.
Strozyk, Michal +3 more
core +1 more source

