Results 41 to 50 of about 630 (149)
2,8-Dichloro-6H,12H-5,11-ethanodibenzo[b,f][1,5]diazocine
Acta Crystallographica Section E, 2008 In the molecule of the title compound, C16H14Cl2N2, the ethano-strapped 2,8-dichloro analogue of Tröger's base, the dihedral angle between the two benzene rings is 87.01 (3)°.
Masoud Faroughi +2 more
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Beyond the Simple Copper(II) Coordination Chemistry with Quinaldinate and Secondary Amines
Molecules, 2020 Copper(II) acetate has reacted in methanol with quinaldinic acid (quinoline-2-carboxylic acid) to form [Cu(quin)2(CH3OH)]∙CH3OH (1) (quin− = an anionic form of the acid) with quinaldinates bound in a bidentate chelating manner.
Barbara Modec, Nina Podjed, Nina Lah
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5,11-Dimethyldibenzo[b,f][1,5]diazocine-6,12(5H,11H)-dione
Acta Crystallographica Section E, 2008 In the molecule of the title compound, C16H14N2O2, an N,N′-dimethyldianthranilide, the two methyl groups are disordered over two positions; site occupation factors were kept fixed as 0.75:0.25 and 0.65:0.35.
Andrew C. Try +2 more
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Acta Crystallographica Section E: Crystallographic CommunicationsThe crystal structure of the title compound, C20H14N4O4, was previously reported at 220 K [Businski et al. (2025). Chem. Eur. J. A71, 3–8], where it crystallizes in the monoclinic space group P21/c with one crystallographically independent molecule in a ...
Christian Näther +2 more
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2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
Acta Crystallographica Section E, 2008 The title compound, C15H10Br2Cl2N2, a 2,8-dibromo-4,10-dichloro Tröger's base analogue derived from 4-bromo-2-chloroaniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo ...
Andrew C. Try +2 more
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Diethyl 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-1,7-dicarboxylate
Acta Crystallographica Section E, 2009 In the molecule of the title compound, C21H22N2O4, the 1,7-diethyl ester analogue of Tröger's base, the dihedral angle between the two benzene rings is 93.16 (3)°; the molecule is C2 symmetric.
M. Delower H. Bhuiyan +2 more
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Dimethyl 6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diacetate
Acta Crystallographica Section E, 2008 The asymmetric unit of the title compound, C21H22N2O4, a Tröger's base analogue derived from methyl 4-aminophenylacetate, contains two crystallographically independent molecules with dihedral angles of 88.44 (5) and 88.68 (6)° ...
Andrew C. Try +2 more
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5,11-Ditosyl-5H,11H-dibenzo[b,f][1,5]diazocine-6,12-dione acetic acid hemisolvate
Acta Crystallographica Section E, 2013 The molecular structure of the title compound, C28H22N2O6S2·0.5CH3COOH, is built up from three fused rings, two six and one eight membered. The eight-membered ring shows a boat conformation and the dihedral angle between the two benzene groups ...
Najat Abbassi +4 more
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The Pyrolysis of 1,2,3,4,6,7-Hexathia-5,8-diazocine [PDF]
Bulletin of the Chemical Society of Japan, 1990 Abstract Crystals of 1,2,3,4,6,7-hexathia-5,8-diazocine (1,4-S6(NH)2) were transformed around 363 K with a molar enthalpy change of the transformation of 2.40±0.07 kJ mol−1. Crystal systems of the two forms of 1,4-S6(NH)2 were identified to be orthorhombic (α-form) and monoclinic (β-form) below and above this temperature.
Yoshiyuki Kudo +2 more
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Acta Crystallographica Section E, 2008 The title compound, C15H6F8N2, possesses a non-crystallographic twofold axis. The dihedral angle between the two benzene rings is 98.4 (2)°. The crystal structure involves intermolecular C—H...F hydrogen bonds.
Sergey Sergeyev +3 more
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