Results 41 to 50 of about 978 (179)

2,8-Dichloro-6H,12H-5,11-ethanodibenzo[b,f][1,5]diazocine

open access: yesActa Crystallographica Section E, 2008
In the molecule of the title compound, C16H14Cl2N2, the ethano-strapped 2,8-dichloro analogue of Tröger's base, the dihedral angle between the two benzene rings is 87.01 (3)°.
Masoud Faroughi   +2 more
doaj   +1 more source

Beyond the Simple Copper(II) Coordination Chemistry with Quinaldinate and Secondary Amines

open access: yesMolecules, 2020
Copper(II) acetate has reacted in methanol with quinaldinic acid (quinoline-2-carboxylic acid) to form [Cu(quin)2(CH3OH)]∙CH3OH (1) (quin− = an anionic form of the acid) with quinaldinates bound in a bidentate chelating manner.
Barbara Modec, Nina Podjed, Nina Lah
doaj   +1 more source

Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] Pathways [PDF]

open access: yes, 2011
In this paper we describe the phosphine-catalyzed [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] annulations of azomethine imines and allenoates. These processes mark the first use of azomethine imines in nucleophilic phosphine catalysis, producing ...
Benitez, Diego   +12 more
core   +2 more sources

Dynamic Control of Nucleic Acids Self‐Assembly and Expression Using Photoswitches

open access: yesChemistry – A European Journal, EarlyView.
We review here the recent progress made in the design of molecular photoswitches, and highlight their implementation for the dynamic control over nucleic acids self‐assembly and expression. ABSTRACT Synthetic nucleic acids have become readily available and now constitute versatile building blocks in materials science—where they can be used to engineer ...
Noemí Nogal   +4 more
wiley   +1 more source

5,11-Dimethyldibenzo[b,f][1,5]diazocine-6,12(5H,11H)-dione

open access: yesActa Crystallographica Section E, 2008
In the molecule of the title compound, C16H14N2O2, an N,N′-dimethyldianthranilide, the two methyl groups are disordered over two positions; site occupation factors were kept fixed as 0.75:0.25 and 0.65:0.35.
Andrew C. Try   +2 more
doaj   +1 more source

Reproductive Mechanisms Influenced by a Diazocine

open access: yesExperimental Biology and Medicine, 1965
Summary2,8-Dichloro-6,12-diphenyl-dibenzo[b,f][l,5] diazocine completely inhibited pregnancy when administered either orally or subcutaneously to female rats at doses as low as 0.5 mg daily for 7 days at time of mating. At higher doses, single treatments prior to completion of implantation were equally effective.
G W, Duncan, S C, Lyster, J B, Wright
openaire   +2 more sources

A Density Functional Theory Study of the Structural Preferences of Type B Heteropentalene Mesomeric Betaines and Their Non‐Aromatic Azacyclooctatetraene Isomers

open access: yesJournal of Heterocyclic Chemistry, Volume 63, Issue 5, Page 778-784, May 2026.
DFT has been used to rationalize the relative stabilities of the Type B heteropentalene mesomeric betaines (HMBs) and their azacyclooctatetraene isomers; the tetraaza and triaza HMBs are generally expected to be thermodynamically more stable than their azacyclooctatetraene isomers, whereas the converse is true for diaza systems.
Jake Bell   +2 more
wiley   +1 more source

Novel photochromic liquid crystals [PDF]

open access: yes, 2016
The combination of photochromic units and liquid crystal mesogens has over the years been investigated intensively. However the focus of this work has been on very few photochromic groups.
Hussey, James
core   +3 more sources

Synthesis and crystal structure of tetramethyl (E)-4,4′-(ethene-1,2-diyl)bis(5-nitrobenzene-1,2-dicarboxylate)

open access: yesActa Crystallographica Section E: Crystallographic Communications
The title compound, C22H18N2O12, was obtained as a by-product during the planned synthesis of 1,2-bis(2-nitro-4,5-dimethyl phthalate)ethane by oxidative dimerization starting from dimethyl-4-methyl-5-nitro phthalate.
Artjom Businski   +4 more
doaj   +1 more source

2,8-Dibromo-4,10-dichloro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine

open access: yesActa Crystallographica Section E, 2008
The title compound, C15H10Br2Cl2N2, a 2,8-dibromo-4,10-dichloro Tröger's base analogue derived from 4-bromo-2-chloroaniline, has a dihedral angle of 110.9 (10)° between the two aryl rings, the largest yet measured for a simple dibenzo ...
Andrew C. Try   +2 more
doaj   +1 more source

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