The reactivity of α,β-unsaturated carboxylic acids. Part XVI. The kinetics of the reaction of cycloalkenecarboxylic and cycloalkenylacetic acids with diazodiphenylmethane in various alcohols [PDF]
Journal of the Serbian Chemical Society, 2002 The rate constants for the reaction of diazodiphenylmethane with 1-cyclopentenecarboxylic, 1-cycloheptenecarboxylic, cyclopent-1-enylacetic and cyclohept-1-enylacetic acids were determined in eight alcohols at 30 ºC using the appropriate UV-spectroscopic
Ušćumlić Gordana S. +2 more
doaj +1 more source
Al-Kitab Journal for Pure Sciences, 2023 Alkaline hydrolysis rates coefficients for the series of methyl 3-(7-substituted-1-naphthyl) propynoate was calculated in 70%v/v dimethylsulphoxide-water at various temperatures (25,30,40, and 50̊ C).
Khalaf D. F. Ghadir +3 more
doaj +1 more source
Kinetics and mechanism of the reaction of substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane in dimethylformamide [PDF]
Journal of Chemical Research, 2000 Correlation of the data for the reaction of 11 substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane (DDM) in dimethylformamide (DMF) with calculated atomic charges on the carboxylic group showed that the reaction in this solvent may proceed via a concerted transition state.
Jovanović, Bratislav +4 more
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Recent Developments in the Biosynthesis of Aziridines
ChemBioChem, Volume 25, Issue 16, August 19, 2024.Aziridines are highly strained three‐membered rings comprised of two carbon atoms and one nitrogen atom. Natural products containing aziridines have been known for decades and used as drugs, but the biological origins of the aziridine ring were unknown until 2021.
Sabina J. Maurer +2 more
wiley +1 more source
The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted phenyl)acetic acids [PDF]
Journal of the Serbian Chemical Society, 2004 The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic ...
VERA V. KRSTIC +2 more
doaj
The reactivity of a,b-unsaturated carboxylic acids. Part XVI. The kinetics of the reaction of cycloalkenylcarboxylic and cycloalkenylacetic acids with diazodiphenylmethane in various alcohols [PDF]
Journal of the Serbian Chemical Society, 2002 The rate constants for the reaction of diazodiphenylmethane with 1-cyclopentenecarboxylic, 1-cycloheptenecarboxylic, cyclopent-1-enylacetic and cyclohept-1-enylacetic acids were determined in eight alcohols at 30°C using the appropriate UV-spectroscopic ...
VERA V. KRSTIC +2 more
doaj
Reactivity of beta-aroylacrylic acids with diazodiphenylmethane
, 1998 The rate constants for 10 trans-substituted beta-aroylacrylic acids in their reaction with diazodiphenylmethane (DDM) were determined in ethanol at 30 degrees C. The intention was to study the transmission of electronic effects of substituents on the phenyl nuclei to the carboxylic group reaction center, through the -C(=O)-CH=CH-group.
Stevović, Ljubomir S. +4 more
openaire +1 more source
A Kinetic Characterization of the Reactions of Anion Radicals of Diazodiphenylmethane in Acetonitrile. [PDF]
Acta Chemica Scandinavica, 1981 Vernon D. Parker +4 more
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A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex. [PDF]
Chemistry, 2020 DeJesus JF, Jenkins DM.
europepmc +1 more source
The Initiation of Acid-Catalyzed Decomposition of Diazodiphenylmethane by Cation Radical Reactions. [PDF]
Acta Chemica Scandinavica, 1987 Jan M. Bakke +4 more
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