Results 51 to 60 of about 5,925,089 (286)

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

Advanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez, Alejandro Orellana‐Silla, Marta Galbiati, Efrén Navarro‐Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio‐Giménez, Sergio Tatay, Carlos Martí‐Gastaldo   +9 more
wiley   +1 more source

Historic records of organic compounds from a high Alpine glacier: influences of biomass burning, anthropogenic emissions, and dust transport [PDF]

Atmospheric Chemistry and Physics, 2016
Historic records of α-dicarbonyls (glyoxal, methylglyoxal), carboxylic acids (C6–C12 dicarboxylic acids, pinic acid, p-hydroxybenzoic acid, phthalic acid, 4-methylphthalic acid), and ions (oxalate, formate, calcium) were determined with annual ...
C. Müller-Tautges, A. Eichler, A. Eichler, M. Schwikowski, M. Schwikowski, M. Schwikowski, G. B. Pezzatti, M. Conedera, T. Hoffmann   +8 more
doaj   +1 more source

Nanozymes for Energy and Environmental Sustainability

Advanced Science, EarlyView.
At present, the widely used nanozymes are oxidoreductase and hydrolase, which have proved to have great application prospects in energy and environment. ABSTRACT Nanozymes have shown remarkable promise in addressing pressing challenges in energy and environmental sustainability.
Xiaoqi Li, Jinxing Chen, Shaojun Dong
wiley   +1 more source

Synergistic Hydrogen‐Bonding and Covalent Crosslinking in Polybenzimidazole Membranes for Wide‐Temperature Anhydrous Fuel Cells

Advanced Science, EarlyView.
A dual‐network architecture combining a thermally reinforced hydrogen‐bonding matrix with an amine‐anhydride covalent framework was constructed in Tröger's Base (TB)‐functionalized polybenzimidazoles. This design yielded the TBAm‐PBI‐TB membrane with high acid uptake (469.5%), anhydrous conductivity (264.7 mS cm−1), and robust stability.
Junming Dai, Jianming Zhong, Jinpeng Luo, Yuxing Song, Fan Hu, Young Moo Lee, Yongbing Zhuang   +6 more
wiley   +1 more source

Thermodynamic properties and cloud droplet activation of a series of oxo-acids [PDF]

Atmospheric Chemistry and Physics, 2010
We have investigated the thermodynamic properties of four aliphatic oxo-dicarboyxlic acids identified or thought to be present in atmospheric particulate matter: oxosuccinic acid, 2-oxoglutaric acid, 3-oxoglutaric acid, and 4-oxopimelic acid.
M. Frosch, A. A. Zardini, S. M. Platt, L. Müller, M.-C. Reinnig, T. Hoffmann, M. Bilde   +6 more
doaj   +1 more source

Pyrazine-2,3-dicarboxylic acid

Acta Crystallographica Section E Structure Reports Online, 2004
The title compound, C6H4N2O4, is a new unsolvated form of pyrazine-2,3-di­carboxyl­ic acid. The asymmetric unit contains two independent mol­ecules with different geometry. The planes of the carboxyl­ic groups make dihedral angles with the planar pyrazine rings of 22.7 (2) and 50.0 (2)° in one mol­ecule, and 9.7 (2) and 79.1 (2)° in the other.
Thathan Premkumar, Subbiah Govindarajan, Wojciech Starosta, Janusz Leciejewicz   +3 more
openaire   +1 more source

Enhanced Energy Transfer from a Metal–Organic Framework to a Highly Confined Organic Phosphorescent Dye

Advanced Science, EarlyView.
A phosphorescent dye was designed to fit in a hand‐to‐glove fashion into the 1D‐pore channels of MIL‐68(In). We synthesized MIL‐68(In) as powder and thin films, loaded the dye into the pores with controlled packing, and found that the phosphorescence and quantum yield are enhanced.
Bahram Hosseini Monjezi, Thomas Kasper, Gloria Hong, Changfeng Si, Robert Oestreich, Oliver Weingart, Peter G. Weidler, Christof Wöll, Eli Zysman‐Colman, Christoph Janiak, Stefan Bräse, Klaus Müller‐Buschbaum, Alexander Knebel   +12 more
wiley   +1 more source

Chemical Characterization of Water-Soluble Organic Acids in Size-Segregated Particles at a Suburban Site in Saitama, Japan

Asian Journal of Atmospheric Environment, 2009
Saturated n-dicarboxylic acids (C2-C7, C9), unsaturated dicarboxylic acids (maleic, fumaric, phthalic acid), ketocarboxylic acids (pyruvic, glyoxylic acid), and dicarbonyls (glyoxal, methylglyoxal) were determined in size-segregated samples with a high ...
Linfa Bao , Kazuhiko Sakamoto
doaj   +1 more source

Main‐Chain Ion‐Pair Polybenzimidazole Membranes Enabling Reduced‐Temperature HT‐PEMFC Operation (Down to 120°C)

Advanced Energy Materials, EarlyView.
Embedding imidazolium‐biphosphate ion pairs directly into the polybenzimidazole main chain simultaneously stabilizes phosphoric acid and preserves continuous proton transport pathways. Strong ion‐pair and hydrogen‐bond interactions suppress acid leaching while maintaining high conductivity, enabling stable and durable high‐temperature fuel cell ...
Huina Lin, Brian C. Benicewicz
wiley   +1 more source

Quinoline based receptor in fluorometric discrimination of carboxylic acids

Beilstein Journal of Organic Chemistry, 2008
Quinoline and naphthalene-based fluororeceptors 1 and 2 have been designed and synthesized for detection of hydroxy carboxylic acids in less polar solvents.
Kumaresh Ghosh, Suman Adhikari, Asoke P. Chattopadhyay, Purnendu Roy Chowdhury   +3 more
doaj   +1 more source